(Q38605492)

4 September 2017

Catalysis of Radical Reactions: A Radical Chemistry Perspective (English)

1 reference

4 September 2017

1

Armido Studer

1 reference

4 September 2017

Dennis P Curran

2

1 reference

PubMed ID

26459814

4 September 2017

language of work or name

English

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publication date

13 October 2015

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Angewandte Chemie International Edition

4 September 2017

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volume

55

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4 September 2017

58-102

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4 September 2017

1

1 reference

The persistent radical effect in organic synthesis

4 September 2017

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

The Persistent Radical Effect: A Principle for Selective Radical Reactions and Living Radical Polymerizations

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Persistent carbon-centered radicals

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Why are organotin hydride reductions of organic halides so frequently retarded? Kinetic studies, analyses, and a few remedies

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Palladium-catalyzed intramolecular iodine-transfer reactions in the presence of β-hydrogen atoms.

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Intermolecular atom transfer radical addition to olefins mediated by oxidative quenching of photoredox catalysts

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Intermolecular Visible-Light Photoredox Atom-Transfer Radical [3+2]-Cyclization of 2-(Iodomethyl)cyclopropane-1,1-dicarboxylate with Alkenes and Alkynes

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

The frequently overlooked importance of solvent in free radical syntheses.

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Thiyl radicals in organic synthesis

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Visible light photoredox catalysis: applications in organic synthesis

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

On the mechanism of photocatalytic reactions with eosin Y.

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Characterizing Chain Processes in Visible Light Photoredox Catalysis

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Redox mediators in visible light photocatalysis: photocatalytic radical thiol-ene additions.

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Photo-organocatalysis of atom-transfer radical additions to alkenes

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Radical reactions of borohydrides

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Iron-catalyzed reactions in organic synthesis

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Factors Controlling the Addition of Carbon-Centered Radicals to Alkenes-An Experimental and Theoretical Perspective

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Chiral Brønsted acids in enantioselective carbonyl activations--activation modes and applications

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Synthesis and reactions of N-heterocyclic carbene boranes

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Polarity reversal catalysis in radical reductions of halides by N-heterocyclic carbene boranes.

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

A short total synthesis of (±)-epimeloscine and (±)-meloscine enabled by a cascade radical annulation of a divinylcyclopropane

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Radical [3 + 2]-annulation of divinylcyclopropanes: rapid synthesis of complex meloscine analogs

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

The electron is a catalyst

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Transition-metal-free coupling reactions.

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Base-Catalyzed Synthesis of Substituted Indazoles under Mild, Transition-Metal-Free Conditions

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Redox catalysis in organic electrosynthesis: basic principles and recent developments.

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Photooxidizing chromium catalysts for promoting radical cation cycloadditions

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Merging photoredox catalysis with organocatalysis: the direct asymmetric alkylation of aldehydes

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Enantioselective alpha-trifluoromethylation of aldehydes via photoredox organocatalysis

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Visible light photoredox catalysis with transition metal complexes: applications in organic synthesis

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Endo-selective Pd-catalyzed silyl methyl Heck reaction

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Palladium-catalyzed, ring-forming aromatic C-H alkylations with unactivated alkyl halides

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Atom transfer radical addition and polymerization reactions catalyzed by ppm amounts of copper complexes

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Synthetic applications of photoredox catalysis with visible light

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

The photocatalyzed Meerwein arylation: classic reaction of aryl diazonium salts in a new light

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Asymmetric catalysis activated by visible light

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Nitroxides: applications in synthesis and in polymer chemistry

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Organocatalysis in radical chemistry. Enantioselective alpha-oxyamination of aldehydes

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

A general approach to the enantioselective α-oxidation of aldehydes via synergistic catalysis

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

The Intramolecular Asymmetric Allylation of Aldehydes via Organo-SOMO Catalysis: A Novel Approach to Ring Construction

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Enantioselective alpha-arylation of aldehydes via organo-SOMO catalysis. An ortho-selective arylation reaction based on an open-shell pathway

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Enantioselective intramolecular Friedel-Crafts-type alpha-arylation of aldehydes.

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Nature of intermediates in organo-SOMO catalysis of alpha-arylation of aldehydes

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Enantioselective organocatalytic singly occupied molecular orbital activation: the enantioselective alpha-enolation of aldehydes

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Enantioselective organo-SOMO cascade cycloadditions: a rapid approach to molecular complexity from simple aldehydes and olefins

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Enantioselective organo-SOMO cycloadditions: a catalytic approach to complex pyrrolidines from olefins and aldehydes

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Enantioselective intramolecular aldehyde α-alkylation with simple olefins: direct access to homo-ene products

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Photoredox activation for the direct β-arylation of ketones and aldehydes

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Direct β-alkylation of aldehydes via photoredox organocatalysis

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Direct β-functionalization of cyclic ketones with aryl ketones via the merger of photoredox and organocatalysis

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Enantioselective α-benzylation of aldehydes via photoredox organocatalysis

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Enantioselective direct α-amination of aldehydes via a photoredox mechanism: a strategy for asymmetric amine fragment coupling

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Enantioselective aldehyde alpha-nitroalkylation via oxidative organocatalysis.

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Organocatalysis by N-heterocyclic carbenes

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Employing homoenolates generated by NHC catalysis in carbon-carbon bond-forming reactions: state of the art.

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Organocatalytic umpolung: N-heterocyclic carbenes and beyond

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Exploiting Acyl and Enol Azolium Intermediates via NHeterocyclic Carbene Catalyzed Reactions of Alpha-Reducible Aldehydes

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Acyl anion free N-heterocyclic carbene organocatalysis

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

On the mechanism of N-heterocyclic carbene-catalyzed reactions involving acyl azoliums

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Enantioselective N-heterocyclic carbene-catalyzed β-hydroxylation of enals using nitroarenes: an atom transfer reaction that proceeds via single electron transfer

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

N-heterocyclic carbene-catalyzed radical reactions for highly enantioselective β-hydroxylation of enals.

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Biomimetic carbene-catalyzed oxidations of aldehydes using TEMPO.

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Catalysis with N-heterocyclic carbenes under oxidative conditions

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Catalytic enantioselective radical cyclization via regiodivergent epoxide opening

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Enantioselective cross-coupling of meso-epoxides with aryl halides.

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Reductive umpolung reactions with low-valent titanium catalysts.

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

A practical and catalytic reductive olefin coupling

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Functionalized olefin cross-coupling to construct carbon-carbon bonds.

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Fe(III)/NaBH4-mediated free radical hydrofluorination of unactivated alkenes

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Iron(III)/NaBH4-mediated additions to unactivated alkenes: synthesis of novel 20'-vinblastine analogues

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

The promise and challenge of iron-catalyzed cross coupling.

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Coming of age: sustainable iron-catalyzed cross-coupling reactions

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Low-valent iron-catalyzed C-C bond formation-addition, substitution, and C-H bond activation.

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

1,n-Hydrogen-atom transfer (HAT) reactions in which n≠5: an updated inventory

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Cross-dehydrogenative coupling (CDC): exploring C-C bond formations beyond functional group transformations

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Recent advances of transition-metal catalyzed radical oxidative cross-couplings.

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Iron-catalyzed oxidative C-H/C-H cross-coupling: an efficient route to α-quaternary α-amino acid derivatives

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Iron-catalyzed oxidative cross-coupling of phenols and alkenes.

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Macromolecular engineering by atom transfer radical polymerization

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Cobalt-catalyzed trimethylsilylmethylmagnesium-promoted radical alkenylation of alkyl halides: a complement to the Heck reaction.

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Olefinic C-H functionalization through radical alkenylation

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Cobalt-mediated cross-coupling reactions of primary and secondary alkyl halides with 1-(trimethylsilyl)ethenyl- and 2-trimethylsilylethynylmagnesium reagents.

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Cobalt-catalyzed cross-coupling reactions of alkyl halides with allylic and benzylic Grignard reagents and their application to tandem radical cyclization/cross-coupling reactions.

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

N-heterocyclic carbene ligands in cobalt-catalyzed sequential cyclization/cross-coupling reactions of 6-halo-1-hexene derivatives with Grignard reagents.

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Metalloradical approach to 2H-chromenes.

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Regioselective synthesis of multisubstituted furans via metalloradical cyclization of alkynes with α-diazocarbonyls: construction of functionalized α-oligofurans.

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Mechanism of cobalt(II) porphyrin-catalyzed C-H amination with organic azides: radical nature and H-atom abstraction ability of the key cobalt(III)-nitrene intermediates.

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Chemoselective amination of propargylic C(sp³)-H bonds by cobalt(II)-based metalloradical catalysis

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Cross-coupling reaction of alkyl halides with grignard reagents catalyzed by Ni, Pd, or Cu complexes with pi-carbon ligand(s).

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Stille cross-couplings of unactivated secondary alkyl halides using monoorganotin reagents

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Nickel-catalyzed asymmetric cross-couplings of racemic propargylic halides with arylzinc reagents

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Nickel/bis(oxazoline)-catalyzed asymmetric Kumada reactions of alkyl electrophiles: cross-couplings of racemic alpha-bromoketones

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Enantioselective alkenylation via nickel-catalyzed cross-coupling with organozirconium reagents

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Catalytic enantioselective cross-couplings of secondary alkyl electrophiles with secondary alkylmetal nucleophiles: Negishi reactions of racemic benzylic bromides with achiral alkylzinc reagents

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Nickel-catalyzed carbon-carbon bond-forming reactions of unactivated tertiary alkyl halides: Suzuki arylations

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Nickel/bis(oxazoline)-catalyzed asymmetric Negishi arylations of racemic secondary benzylic electrophiles to generate enantioenriched 1,1-diarylalkanes

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Catalytic enantioselective cyclization/cross-coupling with alkyl electrophiles

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Stereoconvergent arylations and alkenylations of unactivated alkyl electrophiles: catalytic enantioselective synthesis of secondary sulfonamides and sulfones

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Nickel-catalyzed Negishi arylations of propargylic bromides: a mechanistic investigation

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Evidence for a NiI active species in the catalytic cross-coupling of alkyl electrophiles

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Nickel-catalyzed selective oxidative radical cross-coupling: an effective strategy for inert Csp3-H functionalization.

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Mechanism and selectivity in nickel-catalyzed cross-electrophile coupling of aryl halides with alkyl halides

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Methods and Mechanisms for Cross-Electrophile Coupling of Csp(2) Halides with Alkyl Electrophiles

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Dual catalysis. Single-electron transmetalation in organoboron cross-coupling by photoredox/nickel dual catalysis

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Single-electron transmetalation: an enabling technology for secondary alkylboron cross-coupling

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Dual catalysis. Merging photoredox with nickel catalysis: coupling of α-carboxyl sp³-carbons with aryl halides

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Merging photoredox and nickel catalysis: decarboxylative cross-coupling of carboxylic acids with vinyl halides.

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Decarboxylative acylation of indolines with α-keto acids under palladium catalysis: a facile strategy for the synthesis of 7-substituted indoles.

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

A "Renaissance" in radical trifluoromethylation

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Copper-catalyzed trifluoromethylation of unactivated olefins

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Iron(II)-catalyzed trifluoromethylation of potassium vinyltrifluoroborates

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Copper-catalyzed intermolecular cyanotrifluoromethylation of alkenes.

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Copper-catalyzed oxytrifluoromethylation of unactivated alkenes.

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Copper-catalyzed oxidative Heck reactions between alkyltrifluoroborates and vinyl arenes

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Silver-catalyzed synthesis of 3-phosphorated coumarins via radical cyclization of alkynoates and dialkyl H-phosphonates.

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Silver-catalyzed radical aminofluorination of unactivated alkenes in aqueous media

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Silver-catalyzed radical phosphonofluorination of unactivated alkenes

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Silver-catalyzed decarboxylative fluorination of aliphatic carboxylic acids in aqueous solution.

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Highly Asymmetric Intramolecular Cyclopropanation of Acceptor-Substituted Diazoacetates by Co(II)-Based Metalloradical Catalysis: Iterative Approach for Development of New-Generation Catalysts

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

Potassium tert-butoxide mediated Heck-type cyclization/isomerization–benzofurans from organocatalytic radical cross-coupling reactions

21 January 2018

1 reference

https://api.crossref.org/works/10.1002%2FANIE.201505090

21 January 2018

Identifiers

DOI

10.1002/ANIE.201505090

1 reference

4 September 2017

1 reference

PubMed ID

26459814