(Q35022500)

5 August 2017

title

A gold-catalyzed alkyne-diol cycloisomerization for the synthesis of oxygenated 5,5-spiroketals (English)

1 reference

5 August 2017

Sami F Tlais

1

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5 August 2017

Gregory B Dudley

series ordinal

2

1 reference

5 August 2017

publication date

4 May 2011

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Beilstein Journal of Organic Chemistry

5 August 2017

published in

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5 August 2017

volume

7

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5 August 2017

page(s)

570-577

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A striking exception to the chelate model for acyclic diastereocontrol: efficient access to a versatile propargyl alcohol for chemical synthesis

5 August 2017

cites work

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3107449

Total synthesis of bryostatin 16 using atom-economical and chemoselective approaches

8 July 2018

1 reference

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Asymmetric synthesis of naturally occurring spiroketals

8 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3107449

A gold(I)-catalyzed intramolecular reaction of propargylic/homopropargylic alcohols with oxirane

8 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3107449

Nonanomeric spiroketals in natural products: structures, sources, and synthetic strategies

8 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3107449

The atom economy--a search for synthetic efficiency

8 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3107449

Stereocontrol of 5,5-spiroketals in the synthesis of cephalosporolide H epimers

8 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3107449

Formal total synthesis of okadaic acid via regiocontrolled gold(I)-catalyzed spiroketalizations

25 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3107449

Pd(II)-mediated alkynediol spiroketalization: first total synthesis of (-)-cephalosporolide E and (+)-cephalosporolide F.

25 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3107449

Ring opening/fragmentation of dihydropyrones for the synthesis of homopropargyl alcohols

25 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3107449

Gold(I)-catalyzed synthesis of dihydropyrans

25 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3107449

Tandem nucleophilic addition/fragmentation reactions and synthetic versatility of vinylogous acyl triflates.

25 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3107449

Highly efficient access to strained bicyclic ketals via gold-catalyzed cycloisomerization of bis-homopropargylic diols.

25 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3107449

Palladium-catalyzed DYKAT of vinyl epoxides: enantioselective total synthesis and assignment of the configuration of (+)-Broussonetine G.

25 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3107449

Syntheses of the eastern halves of ritterazines B, F, G, and H, leading to reassignment of the 5,5-spiroketal stereochemistry of ritterazines B and F

25 October 2018

1 reference

12 December 2020

Gold-catalyzed tandem cycloisomerization-hydroalkoxylation of homopropargylic alcohols

1 reference

12 December 2020

Stereodefined Homopropargyl Amines by Tandem Nucleophilic Addition/Fragmentation of Dihydropyridone Triflates

1 reference

12 December 2020

An alkyne strategy for the asymmetric synthesis of natural products: application to (+)-spirolaxine methyl ether

1 reference

12 December 2020

An extremely facile synthesis of furans, pyrroles, and thiophenes by the dehydrative cyclization of propargyl alcohols

1 reference

12 December 2020

Synthesis of the spiroacetal-containing anti-Helicobacter pylori agents CJ-12,954 and CJ-13,014

1 reference

12 December 2020

Synthesis of Chiral Spiroacetals from Carbohydrates

1 reference

12 December 2020

Marine natural products

1 reference

12 December 2020

Metal-catalyzed regioselective oxy-functionalization of internal alkynes: an entry into ketones, acetals, and spiroketals

1 reference

12 December 2020

Au-catalyzed cyclization of monopropargylic triols: an expedient synthesis of monounsaturated spiroketals

1 reference

12 December 2020

Room temperature intramolecular hydro-O-alkylation of aldehydes: sp3 C-H functionalization via a Lewis acid catalyzed tandem 1,5-hydride transfer/cyclization

1 reference

12 December 2020

Ring opening of cyclic vinylogous acyl triflates using stabilized carbanion nucleophiles: claisen condensation linked to carbon-carbon bond cleavage

1 reference

12 December 2020

Identifiers

DOI

10.3762/BJOC.7.66

1 reference

5 August 2017

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5 August 2017

1 reference