(Q35857313)

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Chiral N-Heterocyclic Carbene Catalyzed Annulations of Enals and Ynals with Stable Enols: A Highly Enantioselective Coates-Claisen Rearrangement.

scientific article published on 29 February 2012

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Europe PubMed Central

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27 January 2020

Chiral N-Heterocyclic Carbene Catalyzed Annulations of Enals and Ynals with Stable Enols: A Highly Enantioselective Coates-Claisen Rearrangement (English)

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27 January 2020

enantioselectivity

1 reference

based on heuristic

inferred from title

1 reference

based on heuristic

inferred from title

Jessada Mahatthananchai

1

1 reference

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27 January 2020

author name string

Juthanat Kaeobamrung

2

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27 January 2020

Jeffrey W Bode

3

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27 January 2020

publication date

29 February 2012

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27 January 2020

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27 January 2020

2

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27 January 2020

2

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27 January 2020

494-503

1 reference

Europe PubMed Central

PMC publication ID

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27 January 2020

The effect of the N-mesityl group in NHC-catalyzed reactions

1 reference

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Asymmetric synthesis of allenyl oxindoles and spirooxindoles by a catalytic enantioselective Saucy-Marbet Claisen rearrangement

1 reference

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Gateway synthesis of daphnane congeners and their protein kinase C affinities and cell-growth activities

1 reference

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Employing homoenolates generated by NHC catalysis in carbon-carbon bond-forming reactions: state of the art.

1 reference

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27 July 2018

Carbene catalysts

1 reference

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27 July 2018

On the role of CO2 in NHC-catalyzed oxidation of aldehydes

1 reference

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Transition-state charge stabilization through multiple non-covalent interactions in the guanidinium-catalyzed enantioselective Claisen rearrangement

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3314221

27 July 2018

α,β-Unsaturated acyl azoliums from N-heterocyclic carbene catalyzed reactions: observation and mechanistic investigation.

1 reference

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27 July 2018

Chiral N-heterocyclic carbene-catalyzed generation of ester enolate equivalents from α,β-unsaturated aldehydes for enantioselective Diels–Alder reactions

1 reference

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27 July 2018

Attractive noncovalent interactions in asymmetric catalysis: Links between enzymes and small molecule catalysts

1 reference

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27 July 2018

An enantioselective Claisen rearrangement catalyzed by N-heterocyclic carbenes

1 reference

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27 July 2018

Design of a bisamidinium claisen rearrangement catalyst for monodentate substrates

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3314221

27 July 2018

Enantioselective Claisen rearrangements with a hydrogen-bond donor catalyst

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3314221

27 July 2018

Observation of an acryloyl-thiamin diphosphate adduct in the first step of clavulanic acid biosynthesis.

1 reference

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27 July 2018

Metal-free organocatalysis through explicit hydrogen bonding interactions

1 reference

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27 July 2018

Selective stabilization of the chorismate mutase transition state by a positively charged hydrogen bond donor

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3314221

27 July 2018

Reinterpretation of curved Hammett plots in reaction of nucleophiles with aryl benzoates: change in rate-determining step or mechanism versus ground-state stabilization

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3314221

27 July 2018

Hydrolysis of imidazole-2-ylidenes

1 reference

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24 September 2018

Catalytic enantioselective claisen rearrangements of O-allyl β-ketoesters

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3314221

24 September 2018

The total synthesis of (-)-7-deoxyloganin via N-heterocyclic carbene catalyzed rearrangement of α,β-unsaturated enol esters.

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3314221

24 September 2018

Catalytic Asymmetric Claisen Rearrangement of Unactivated Allyl Vinyl Ethers

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3314221

24 September 2018

N-heterocyclic carbene-catalyzed generation of alpha,beta-unsaturated acyl imidazoliums: synthesis of dihydropyranones by their reaction with enolates

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3314221

24 September 2018

Catalytic amide formation with alpha'-hydroxyenones as acylating reagents

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3314221

24 September 2018

Catalytic enantioselective Meerwein-Eschenmoser Claisen rearrangement: asymmetric synthesis of allyl oxindoles

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3314221

24 September 2018

Biomimetic carbene-catalyzed oxidations of aldehydes using TEMPO.

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3314221

24 September 2018

N-heterocyclic carbene-catalyzed redox amidations of alpha-functionalized aldehydes with amines

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3314221

24 September 2018

Nucleophilic carbene and HOAt relay catalysis in an amide bond coupling: an orthogonal peptide bond forming reaction

1 reference

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24 September 2018

Organocatalytic claisen rearrangement: theory and experiment

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3314221

24 September 2018

Enantioselective, cyclopentene-forming annulations via NHC-catalyzed benzoin-oxy-cope reactions

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3314221

24 September 2018

Highly enantioselective azadiene Diels-Alder reactions catalyzed by chiral N-heterocyclic carbenes

1 reference

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24 September 2018

Organocatalyzed conjugate umpolung of alpha,beta-unsaturated aldehydes for the synthesis of gamma-butyrolactones

1 reference

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24 September 2018

Catalytic generation of activated carboxylates: direct, stereoselective synthesis of beta-hydroxyesters from epoxyaldehydes.

1 reference

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24 September 2018

Catalyzed Olefin Isomerization Leading to Highly Stereoselective Claisen Rearrangements of Aliphatic Allyl Vinyl Ethers

1 reference

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24 September 2018

A highly enantioselective catalytic intramolecular Stetter reaction

1 reference

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24 September 2018

Enantioselective Claisen rearrangements: development of a first generation asymmetric acyl-Claisen reaction

1 reference

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24 September 2018

Tandem oxidation of allylic and benzylic alcohols to esters catalyzed by N-heterocyclic carbenes

1 reference

https://pubmed.ncbi.nlm.nih.gov/22468232

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

NHC catalyzed oxidations of aldehydes to esters: chemoselective acylation of alcohols in presence of amines

1 reference

https://pubmed.ncbi.nlm.nih.gov/22468232

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

N-heterocyclic carbene-catalyzed amidation of unactivated esters with amino alcohols

1 reference

https://pubmed.ncbi.nlm.nih.gov/22468232

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Chiral N-heterocyclic carbene catalyzed annulation of α,β-unsaturated aldehydes with 1,3-dicarbonyls

1 reference

https://pubmed.ncbi.nlm.nih.gov/22468232

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Catalytic Kinetic Resolution of Cyclic Secondary Amines

1 reference

https://pubmed.ncbi.nlm.nih.gov/22468232

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Enantioselective N-heterocyclic carbene-catalyzed Michael addition to α,β-unsaturated aldehydes by redox oxidation

1 reference

https://pubmed.ncbi.nlm.nih.gov/22468232

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Enantioselective synthesis of dihydropyridinones via NHC-catalyzed aza-Claisen reaction

1 reference

https://pubmed.ncbi.nlm.nih.gov/22468232

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

N-heterocyclic carbene-catalyzed generation of homoenolates: gamma-butyrolactones by direct annulations of enals and aldehydes

1 reference

https://pubmed.ncbi.nlm.nih.gov/22468232

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Function-oriented synthesis: studies aimed at the synthesis and mode of action of 1alpha-alkyldaphnane analogues

1 reference

https://pubmed.ncbi.nlm.nih.gov/22468232

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

N-Heterocyclic carbene-catalyzed (4+2) cycloaddition/decarboxylation of silyl dienol ethers with α,β-unsaturated acid fluorides

1 reference

https://pubmed.ncbi.nlm.nih.gov/22468232

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Asymmetric claisen rearrangements enabled by catalytic asymmetric Di(allyl) ether synthesis

1 reference

https://pubmed.ncbi.nlm.nih.gov/22468232

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

The Catalytic Enantioselective Claisen Rearrangement of an Allyl Vinyl Ether This work was financially supported by the Deutsche Forschungsgemeinschaft, the Fonds der Chemischen Industrie, and the Dr. Otto Röhm Gedächtnisstiftung. M.H. thanks Prof.

1 reference

https://pubmed.ncbi.nlm.nih.gov/22468232

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Stereoselective synthesis of (E)-alpha,beta-unsaturated esters via carbene-catalyzed redox esterification

1 reference

https://pubmed.ncbi.nlm.nih.gov/22468232

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Synthetic and quantum mechanical studies into the N-heterocyclic carbene catalyzed (4 + 2) cycloaddition

1 reference

https://pubmed.ncbi.nlm.nih.gov/22468232

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Highly stereoselective synthesis of 1,2,3-trisubstituted indanes via oxidative N-heterocyclic carbene-catalyzed cascades

1 reference

https://pubmed.ncbi.nlm.nih.gov/22468232

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

NHC-catalyzed Michael addition to α,β-unsaturated aldehydes by redox activation

1 reference

https://pubmed.ncbi.nlm.nih.gov/22468232

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Gosteli-Claisen rearrangement of propargyl vinyl ethers: cascading molecular rearrangements

1 reference

https://pubmed.ncbi.nlm.nih.gov/22468232

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Conversion of alpha-haloaldehydes into acylating agents by an internal redox reaction catalyzed by nucleophilic carbenes

1 reference

https://pubmed.ncbi.nlm.nih.gov/22468232

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Concise formal synthesis of (-)-7-deoxyloganin via N-heterocyclic carbene catalysed rearrangement of α,β-unsaturated enol esters

1 reference

https://pubmed.ncbi.nlm.nih.gov/22468232

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

The Cu(OTf)2- and Yb(OTf)3-catalyzed Claisen rearrangement of 2-alkoxycarbonyl-substituted allyl vinyl ethers

1 reference

https://pubmed.ncbi.nlm.nih.gov/22468232

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Catalytic generation of activated carboxylates from enals: a product-determining role for the base

1 reference

https://pubmed.ncbi.nlm.nih.gov/22468232

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Identifiers

10.1021/CS300020T

1 reference

Europe PubMed Central

PMC publication ID

https://www.ebi.ac.uk/europepmc/webservices/rest/search?query=EXT_ID:22468232%20AND%20SRC:MED&resulttype=core&format=json

27 January 2020

PMC publication ID

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Europe PubMed Central

PMC publication ID

https://www.ebi.ac.uk/europepmc/webservices/rest/search?query=EXT_ID:22468232%20AND%20SRC:MED&resulttype=core&format=json

27 January 2020

PubMed publication ID

1 reference

Europe PubMed Central

PMC publication ID

https://www.ebi.ac.uk/europepmc/webservices/rest/search?query=EXT_ID:22468232%20AND%20SRC:MED&resulttype=core&format=json

27 January 2020

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