(Q36852312)

16 August 2017

1 reference

title

Direct transition metal-catalyzed functionalization of heteroaromatic compounds (English)

1 reference

16 August 2017

1 reference

Ilya V Seregin

1

1 reference

PMC publication ID

3674790

16 August 2017

Vladimir Gevorgyan

series ordinal

2

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16 August 2017

5 March 2007

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16 August 2017

Chemical Society Reviews

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16 August 2017

36

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16 August 2017

7

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16 August 2017

1173-1193

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Palladium-catalyzed benzene arylation: incorporation of catalytic pivalic acid as a proton shuttle and a key element in catalyst design

16 August 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3674790

Catalytic intermolecular direct arylation of perfluorobenzenes.

29 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3674790

A solution to the 2-pyridyl organometallic cross-coupling problem: regioselective catalytic direct arylation of pyridine N-oxides.

29 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3674790

Concise synthesis of (+/-)-rhazinilam through direct coupling

29 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3674790

Beyond thermodynamic acidity: a perspective on the complex-induced proximity effect (CIPE) in deprotonation reactions

29 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3674790

Palladium-catalyzed arylation and heteroarylation of indolizines

29 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3674790

Catalytic C-h/olefin coupling

29 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3674790

Concise total synthesis of (-)-frondosin B using a novel palladium-catalyzed cyclization

29 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3674790

Hydroheteroarylation of alkynes under mild nickel catalysis.

4 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3674790

Mild aerobic oxidative palladium (II) catalyzed C-H bond functionalization: regioselective and switchable C-H alkenylation and annulation of pyrroles

4 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3674790

Microwave-promoted rhodium-catalyzed arylation of heterocycles through C--H bond activation

4 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3674790

Proton abstraction mechanism for the palladium-catalyzed intramolecular arylation.

4 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3674790

Catalytic direct arylation with aryl chlorides, bromides, and iodides: intramolecular studies leading to new intermolecular reactions

4 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3674790

Highly regioselective arylation of sp3 C-H bonds catalyzed by palladium acetate

4 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3674790

Direct palladium-catalyzed C-2 and C-3 arylation of indoles: a mechanistic rationale for regioselectivity

4 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3674790

Cyclocarbopalladation involving an unusual 1,5-palladium vinyl to aryl shift as termination step: theoretical study of the mechanism.

4 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3674790

Regioselective synthesis of 1,5-diaryl-1H-imidazoles by palladium-catalyzed direct arylation of 1-aryl-1H-imidazoles.

4 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3674790

Direct C-arylation of free (NH)-indoles and pyrroles catalyzed by Ar-Rh(III) complexes assembled in situ

4 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3674790

The kinetic acidity of oligofluorobenzenes correlated with their gas phase deprotonation energies

4 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3674790

Directed palladation: fine tuning permits the catalytic 2-alkenylation of indoles

4 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3674790

Palladium-catalyzed cyclization/carboalkoxylation of alkenyl indoles

4 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3674790

Reactivity of the indole ring in palladium(II) complexes of 2N1O-donor ligands: cyclopalladation and pi-cation radical formation

4 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3674790

Platinum-catalyzed intramolecular alkylation of indoles with unactivated olefins

4 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3674790

Regioselectivity on the palladium-catalyzed intramolecular cyclization of indole derivatives.

4 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3674790

Catalytic C-H bond functionalization with palladiumII: aerobic oxidative annulations of indoles

4 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3674790

Facile synthesis of 2,5-diarylthiazoles via palladium-catalyzed tandem C-H substitutions. Design of tunable light emission and liquid crystalline characteristics

4 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3674790

Regioselective palladium-catalyzed arylation of 3-carboalkoxy furan and thiophene.

4 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3674790

The total synthesis of (-)-amathaspiramide F.

4 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3674790

Intermolecular coupling of isomerizable alkenes to heterocycles via rhodium-catalyzed C-H bond activation

4 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3674790

Palladium-catalyzed multiple arylation of thiophenes.

4 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3674790

Catalytic asymmetric cyclopropanation of heteroaryldiazoacetates

4 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3674790

Annulation of alkenyl-substituted heterocycles via rhodium-catalyzed intramolecular C-H activated coupling reactions.

4 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3674790

Highly Regioselective Catalytic Oxidative Coupling Reactions: Synthetic and Mechanistic Investigations

4 September 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3674790

Room Temperature Palladium-Catalyzed 2-Arylation of Indoles

4 December 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3674790

Oxidative C−H Activation/C−C Bond Forming Reactions: Synthetic Scope and Mechanistic Insights

4 December 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3674790

Microwave-Assisted C−H Bond Activation: A Rapid Entry into Functionalized Heterocycles

4 December 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3674790

Ru-, Rh-, and Pd-catalyzed C-C bond formation involving C-H activation and addition on unsaturated substrates: reactions and mechanistic aspects

4 December 2018

1 reference

12 December 2020

Regioselective palladium-catalyzed arylation of 2-furaldehyde

1 reference

12 December 2020

C-H bond functionalization in complex organic synthesis

1 reference

12 December 2020

Direct C-H bond arylation: selective palladium-catalyzed C2-arylation of N-substituted indoles

1 reference

12 December 2020

Rhodium-catalyzed carbon-carbon bond forming reactions of organometallic compounds

1 reference

12 December 2020

A route to annulated indoles via a palladium-catalyzed tandem alkylation/direct arylation reaction

1 reference

12 December 2020

Anilide ortho-arylation by using C-H activation methodology

1 reference

12 December 2020

Palladium-catalyzed cross-coupling of pyrrole anions with aryl chlorides, bromides, and iodides

1 reference

12 December 2020

Synthesis of polycyclic heterocycles via a one-pot ortho alkylation/direct heteroarylation sequence

1 reference

12 December 2020

Palladium-catalyzed cross-coupling reactions of diazine N-oxides with aryl chlorides, bromides, and iodides

1 reference

12 December 2020

Remarkably selective iridium catalysts for the elaboration of aromatic C-H bonds

1 reference

12 December 2020

Palladium-catalyzed direct arylation of simple arenes in synthesis of biaryl molecules

1 reference

12 December 2020

Palladium-catalyzed asymmetric iodination of unactivated C-H bonds under mild conditions

1 reference

12 December 2020

Palladium-catalyzed regioselective arylation of imidazo[1,2-a]pyrimidine

1 reference

12 December 2020

Palladium-catalyzed intermolecular alkenylation of indoles by solvent-controlled regioselective C-H functionalization

1 reference

12 December 2020

Highly efficient construction of benzene ring in carbazoles by palladium-catalyzed endo-mode oxidative cyclization of 3-(3'-alkenyl)indoles

1 reference

12 December 2020

Direct C-H arylation of (hetero)arenes with aryl iodides via rhodium catalysis

1 reference

12 December 2020

Isotope effects in C-H bond activation reactions by transition metals

1 reference

12 December 2020

Synthesis of Novel Tetracycles via an Intramolecular Heck Reaction with anti-Hydride Elimination

1 reference

12 December 2020

Au(I)-catalyzed annulation of enantioenriched allenes in the enantioselective total synthesis of (-)-rhazinilam

1 reference

12 December 2020

Catalytic coupling of haloolefins with anilides

1 reference

12 December 2020

Heck, direct arylation, and hydrogenation: two or three sequential reactions from a single catalyst

1 reference

12 December 2020

Direct arylation reactions catalyzed by Pd(OH)2/C: evidence for a soluble palladium catalyst

1 reference

12 December 2020

A New Gold-Catalyzed C-C Bond Formation This work was supported by the Deutsche Forschungsgemeinschaft (Ha 1932/5-1, Ha 1932/6-1) and the Fonds der Chemischen Industrie. Gold salts were donated by Degussa-Hüls AG. A.S.K.H. is indebted to Prof. M. Gö

1 reference

12 December 2020

Polymer support assisted selective functionalization of azoles using a palladium-catalyzed coupling reaction

1 reference

12 December 2020

Preparation of annulated nitrogen-containing heterocycles via a one-pot palladium-catalyzed alkylation/direct arylation sequence

1 reference

12 December 2020

Palladium-catalyzed coupling reactions of bromothiophenes at the C-H bond adjacent to the sulfur atom with a new activator system, AgNO3/KF

1 reference

12 December 2020

Mild and general conditions for the cross-coupling of aryl halides with pentafluorobenzene and other perfluoroaromatics

1 reference

12 December 2020

Catalytic C-H arylation of SEM-protected azoles with palladium complexes of NHCs and phosphines

1 reference

12 December 2020

Ruthenium(II) porphyrin-catalyzed amidation of aromatic heterocycles

1 reference

12 December 2020

Pd-catalyzed stereoselective oxidation of methyl groups by inexpensive oxidants under mild conditions: a dual role for carboxylic anhydrides in catalytic C--H bond oxidation

1 reference

12 December 2020

Arylation of heterocycles via rhodium-catalyzed C-H bond functionalization

1 reference

12 December 2020

Catalytic coupling of C-H and C-I bonds using pyridine as a directing group

1 reference

12 December 2020

High-yielding intramolecular direct arylation reactions with aryl chlorides

1 reference

12 December 2020

Identifiers

DOI

10.1039/B606984N

1 reference

16 August 2017

1 reference

PMC publication ID

3674790

16 August 2017

PubMed publication ID

17576484

1 reference

PMC publication ID

3674790