(Q36876714)

English

Mechanistically diverse copper-, silver-, and gold-catalyzed acyloxy and phosphatyloxy migrations: efficient synthesis of heterocycles via cascade migration/cycloisomerization approach

scientific article published on 21 July 2007

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scholarly article

1 reference

Europe PubMed Central

16 August 2017

Mechanistically diverse copper-, silver-, and gold-catalyzed acyloxy and phosphatyloxy migrations: efficient synthesis of heterocycles via cascade migration/cycloisomerization approach (English)

1 reference

Europe PubMed Central

16 August 2017

0 references

author name string

Todd Schwier

1

1 reference

Europe PubMed Central

16 August 2017

Anna W Sromek

2

1 reference

Europe PubMed Central

16 August 2017

Dahrika M L Yap

3

1 reference

Europe PubMed Central

16 August 2017

Dmitri Chernyak

4

1 reference

Europe PubMed Central

16 August 2017

Vladimir Gevorgyan

5

1 reference

Europe PubMed Central

16 August 2017

language of work or name

0 references

publication date

21 July 2007

1 reference

Europe PubMed Central

16 August 2017

Journal of the American Chemical Society

1 reference

Europe PubMed Central

16 August 2017

129

1 reference

Europe PubMed Central

16 August 2017

32

1 reference

Europe PubMed Central

16 August 2017

9868-9878

1 reference

Europe PubMed Central

16 August 2017

1,2-Migration of the thio group in allenyl sulfides: efficient synthesis of 3-thio-substituted furans and pyrroles

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2536635

29 September 2017

Gold-catalyzed 1,2-migration of silicon, tin, and germanium en route to C-2 substituted fused pyrrole-containing heterocycles

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2536635

29 September 2017

Synthesis of cannabidiols via alkenylation of cyclohexenyl monoacetate

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2536635

29 September 2017

1,2-Halogen migration in haloallenyl ketones: regiodivergent synthesis of halofurans

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2536635

29 September 2017

Gold(I)-catalyzed stereoselective olefin cyclopropanation.

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2536635

27 June 2018

1,2-Thio group migration in Rh(II) carbene reactions

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2536635

27 June 2018

A novel 1,2-migration of acyloxy, phosphatyloxy, and sulfonyloxy groups in allenes: efficient synthesis of tri- and tetrasubstituted furans

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2536635

27 June 2018

Pt-catalyzed cyclization/1,2-migration for the synthesis of indolizines, pyrrolones, and indolizinones

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2536635

4 September 2018

Ruthenium-catalyzed [1,n]-metallotropic shift (n = 3, 5) of alkynyl carbene complex intermediates.

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2536635

4 September 2018

A highly efficient preparative method of alpha-ylidene-beta-diketones via Au(III)-catalyzed acyl migration of propargylic esters.

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2536635

4 September 2018

Synthesis of aromatic ketones by a transition metal-catalyzed tandem sequence

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2536635

4 September 2018

Mechanism of the gold(I)-catalyzed Rautenstrauch rearrangement: a center-to-helix-to-center chirality transfer

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2536635

4 September 2018

Platinum- and gold-catalyzed rearrangement reactions of propargyl acetates: total syntheses of (-)-alpha-cubebene, (-)-cubebol, sesquicarene and related terpenes

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2536635

4 September 2018

Efficient synthesis of cyclopentenones from enynyl acetates via tandem Au(I)-catalyzed 3,3-rearrangement and the Nazarov reaction.

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2536635

4 September 2018

Tandem au-catalyzed 3,3-rearrangement-[2 + 2] cycloadditions of propargylic esters: expeditious access to highly functionalized 2,3-indoline-fused cyclobutanes.

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2536635

4 September 2018

Pt-catalyzed pentannulations from in situ generated metallo-carbenoids utilizing propargylic esters

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2536635

4 September 2018

Gold(I)-catalyzed intramolecular acetylenic Schmidt reaction.

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2536635

4 September 2018

Synthesis of 2-cyclopentenones by gold(I)-catalyzed Rautenstrauch rearrangement.

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2536635

4 September 2018

Highly reactive, general, and long-lived catalysts for coupling heteroaryl and aryl chlorides with primary nitrogen nucleophiles

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2536635

4 September 2018

Developments in furan syntheses.

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2536635

4 September 2018

Platinum- and gold-catalyzed cycloisomerization reactions of hydroxylated enynes

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2536635

4 September 2018

Palladium(II)-catalyzed intramolecular 1,4-oxyacyloxylation of conjugated dienes. A stereocontrolled route to fused six-membered lactones and pyrans

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2536635

4 September 2018

Phosphine-mediated reductive condensation of gamma-acyloxy butynoates: a diversity oriented strategy for the construction of substituted furans

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2536635

4 September 2018

Oxasmaragdyrin-ferrocene and oxacorrole-ferrocene conjugates: synthesis, structure, and nonlinear optical properties

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2536635

4 September 2018

Palladium-catalyzed multicomponent coupling of alkynes, imines, and acid chlorides: a direct and modular approach to pyrrole synthesis

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2536635

4 September 2018

Ruthenium-Catalyzed Cyclopropanation of Alkenes Using Propargylic Carboxylates as Precursors of Vinylcarbenoids

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2536635

4 September 2018

2,3,4- or 2,3,5-Trisubstituted Furans: Catalyst-Controlled Highly Regioselective Ring-Opening Cycloisomerization Reaction of Cyclopropenyl Ketones

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2536635

4 September 2018

General and regioselective synthesis of substituted pyrroles by metal-catalyzed or spontaneous cycloisomerization of (Z)-(2-en-4-ynyl)amines

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2536635

4 September 2018

Non-amine-based furan-containing oligoaryls as efficient hole transporting materials

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2536635

4 September 2018

A novel Cu-assisted cycloisomerization of alkynyl imines: efficient synthesis of pyrroles and pyrrole-containing heterocycles.

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2536635

4 September 2018

Synthesis of trisubstituted furans from epoxypropargyl esters by sequential SmI2-promoted reduction-elimination and Pd(II)-catalyzed cycloisomerization

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2536635

4 September 2018

Novel Ruthenium- and Platinum-Catalyzed Sequential Reactions: Synthesis of Tri- and Tetrasubstituted Furans and Pyrroles from Propargylic Alcohols and Ketones

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2536635

4 December 2018

Palladium-catalyzed one-pot synthesis of highly substituted furans by a three-component annulation reaction

1 reference

https://pubmed.ncbi.nlm.nih.gov/17658805

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Base-catalyzed stereoselective isomerization of electron-deficient propargylic alcohols to E-enones

1 reference

https://pubmed.ncbi.nlm.nih.gov/17658805

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

A novel one-pot pyrrole synthesis via a coupling-isomerization-Stetter-Paal-Knorr sequence

1 reference

https://pubmed.ncbi.nlm.nih.gov/17658805

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Free-Radical Ring Contraction of Six-, Seven-, and Eight-Membered Lactones by a 1,2-Shift Mechanism. A Kinetic and (17)O NMR Spectroscopic Study

1 reference

https://pubmed.ncbi.nlm.nih.gov/17658805

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Gold(III) porphyrin-catalyzed cycloisomerization of allenones

1 reference

https://pubmed.ncbi.nlm.nih.gov/17658805

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Preparation of Substituted Alkylpyrroles via Samarium-Catalyzed Three-Component Coupling Reaction of Aldehydes, Amines, and Nitroalkanes

1 reference

https://pubmed.ncbi.nlm.nih.gov/17658805

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Brønsted acid catalyzed addition of phenols, carboxylic acids, and tosylamides to simple olefins

1 reference

https://pubmed.ncbi.nlm.nih.gov/17658805

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Cross and ring-closing metathesis of 1,3-diynes: metallotropic [1,3]-shift of ruthenium carbenes

1 reference

https://pubmed.ncbi.nlm.nih.gov/17658805

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Efficient synthesis of 2-mono- and 2,5-disubstituted furans via the CuI-catalyzed cycloisomerization of alkynyl ketones

1 reference

https://pubmed.ncbi.nlm.nih.gov/17658805

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Gold(I)-catalyzed reaction of 1-(1-alkynyl)-cyclopropyl ketones with nucleophiles: a modular entry to highly substituted furans

1 reference

https://pubmed.ncbi.nlm.nih.gov/17658805

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Versatile direct synthesis of oligosubstituted pyrroles by cycloaddition of alpha-metalated isocyanides to acetylenes

1 reference

https://pubmed.ncbi.nlm.nih.gov/17658805

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Radical contraction of 1,3,2-dioxaphosphepanes to 1,3,2-dioxaphosphorinanes: a kinetic and (17)O NMR spectroscopic study

1 reference

https://pubmed.ncbi.nlm.nih.gov/17658805

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Hydroamination and hydroalkoxylation catalyzed by triflic acid. Parallels to reactions initiated with metal triflates

1 reference

https://pubmed.ncbi.nlm.nih.gov/17658805

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Propargylic Esters in Gold Catalysis: Access to Diversity

1 reference

https://pubmed.ncbi.nlm.nih.gov/17658805

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Syntheses of polysubstituted furans: recent developments

1 reference

https://pubmed.ncbi.nlm.nih.gov/17658805

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Electrochemically Active Polymers for Rechargeable Batteries

1 reference

https://pubmed.ncbi.nlm.nih.gov/17658805

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Room temperature zinc chloride-catalyzed cycloisomerization of Alk-3-yn-1-ones: synthesis of substituted furans

1 reference

https://pubmed.ncbi.nlm.nih.gov/17658805

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

A New Gold-Catalyzed C-C Bond Formation This work was supported by the Deutsche Forschungsgemeinschaft (Ha 1932/5-1, Ha 1932/6-1) and the Fonds der Chemischen Industrie. Gold salts were donated by Degussa-Hüls AG. A.S.K.H. is indebted to Prof. M. Gö

1 reference

https://pubmed.ncbi.nlm.nih.gov/17658805

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

B(C6F5)3-catalyzed allylation of propargyl acetates with allylsilanes

1 reference

https://pubmed.ncbi.nlm.nih.gov/17658805

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Direct Synthesis of Pyrroles from Imines, Alkynes, and Acid Chlorides: An Isocyanide-Mediated Reaction

1 reference

https://pubmed.ncbi.nlm.nih.gov/17658805

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Gold-catalyzed efficient formation of alkenyl enol esters/carbonates from trimethylsilylmethyl-substituted propargyl esters/carbonates

1 reference

https://pubmed.ncbi.nlm.nih.gov/17658805

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Au-catalyzed reaction of propargylic sulfides and dithioacetals

1 reference

https://pubmed.ncbi.nlm.nih.gov/17658805

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

AuI-Catalyzed Tandem [3,3] Rearrangement–Intramolecular Hydroarylation: Mild and Efficient Formation of Substituted Indenes

1 reference

https://pubmed.ncbi.nlm.nih.gov/17658805

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Synthesis of (-)-cubebol by face-selective platinum-, gold-, or copper-catalyzed cycloisomerization: evidence for chirality transfer

1 reference

https://pubmed.ncbi.nlm.nih.gov/17658805

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Pt-catalyzed tandem epoxide fragmentation/pentannulation of propargylic esters

1 reference

https://pubmed.ncbi.nlm.nih.gov/17658805

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

The first successful base-promoted isomerization of propargyl amides to chiral ynamides. Applications in ring-closing metathesis of ene-ynamides and tandem RCM of diene-ynamides

1 reference

https://pubmed.ncbi.nlm.nih.gov/17658805

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Gold(I)-catalyzed synthesis of highly substituted furans

1 reference

https://pubmed.ncbi.nlm.nih.gov/17658805

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Highly efficient and functional-group-tolerant catalysts for the palladium-catalyzed coupling of aryl chlorides with thiols

1 reference

https://pubmed.ncbi.nlm.nih.gov/17658805

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Alkynes as synthetic equivalents to stabilized Wittig reagents: intra- and intermolecular carbonyl olefinations catalyzed by Ag(I), BF3, and HBF4

1 reference

https://pubmed.ncbi.nlm.nih.gov/17658805

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Gold(I) catalyzed isomerization of 5-en-2-yn-1-yl acetates: an efficient access to acetoxy bicyclo[3.1.0]hexenes and 2-cycloalken-1-ones

1 reference

https://pubmed.ncbi.nlm.nih.gov/17658805

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Copper- or phosphine-catalyzed reaction of alkynes with isocyanides. Regioselective synthesis of substituted pyrroles controlled by the catalyst

1 reference

https://pubmed.ncbi.nlm.nih.gov/17658805

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Synthesis of highly substituted furans by the electrophile-induced coupling of 2-(1-alkynyl)-2-alken-1-ones and nucleophiles

1 reference

https://pubmed.ncbi.nlm.nih.gov/17658805

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

C-C-Bond Formation by the Palladium-Catalyzed Cycloisomerization/Dimerization of Terminal Allenyl Ketones: Selectivity and Mechanistic Aspects

1 reference

https://pubmed.ncbi.nlm.nih.gov/17658805

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Catalytic multicomponent reactions for the synthesis of N-aryl trisubstituted pyrroles

1 reference

https://pubmed.ncbi.nlm.nih.gov/17658805

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Identifiers

10.1021/JA072446M

1 reference

Europe PubMed Central

16 August 2017

1 reference

Europe PubMed Central

16 August 2017

1 reference

Europe PubMed Central

16 August 2017

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