(Q37871873)

https://www.ebi.ac.uk/europepmc/webservices/rest/search?query=EXT_ID:21541432%20AND%20SRC:MED&resulttype=core&format=json

30 January 2020

review article

1 reference

title

Biosynthesis via carbocations: theoretical studies on terpene formation (English)

1 reference

https://www.ebi.ac.uk/europepmc/webservices/rest/search?query=EXT_ID:21541432%20AND%20SRC:MED&resulttype=core&format=json

30 January 2020

1

1 reference

https://www.ebi.ac.uk/europepmc/webservices/rest/search?query=EXT_ID:21541432%20AND%20SRC:MED&resulttype=core&format=json

30 January 2020

author name string

Dean J Tantillo

series ordinal

1

1 reference

24 August 2017

4 May 2011

1 reference

https://www.ebi.ac.uk/europepmc/webservices/rest/search?query=EXT_ID:21541432%20AND%20SRC:MED&resulttype=core&format=json

30 January 2020

published in

Natural Product Reports

1 reference

https://www.ebi.ac.uk/europepmc/webservices/rest/search?query=EXT_ID:21541432%20AND%20SRC:MED&resulttype=core&format=json

30 January 2020

volume

28

1 reference

https://www.ebi.ac.uk/europepmc/webservices/rest/search?query=EXT_ID:21541432%20AND%20SRC:MED&resulttype=core&format=json

30 January 2020

issue

6

1 reference

https://www.ebi.ac.uk/europepmc/webservices/rest/search?query=EXT_ID:21541432%20AND%20SRC:MED&resulttype=core&format=json

30 January 2020

page(s)

1035-1053

1 reference

https://www.ebi.ac.uk/europepmc/webservices/rest/search?query=EXT_ID:21541432%20AND%20SRC:MED&resulttype=core&format=json

Cyclization Enzymes in the Biosynthesis of Monoterpenes, Sesquiterpenes, and Diterpenes

30 January 2020

cites work

1 reference

https://api.crossref.org/works/10.1039%2FC1NP00006C

Structural biology and chemistry of the terpenoid cyclases

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC1NP00006C

Understanding the substrate selectivity and the product regioselectivity of Orf2-catalyzed aromatic prenylations.

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC1NP00006C

Computational studies of the farnesyltransferase ternary complex part II: the conformational activation of farnesyldiphosphate

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC1NP00006C

The search for the mechanism of the reaction catalyzed by farnesyltransferase.

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC1NP00006C

Unraveling the Catalytic Pathway of Metalloenzyme Farnesyltransferase through QM/MM Computation

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC1NP00006C

Modeling the E. coli 4-hydroxybenzoic acid oligoprenyltransferase ( ubiA transferase) and characterization of potential active sites

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC1NP00006C

Transition state analysis of model and enzymatic prenylation reactions

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC1NP00006C

The cationic cascade route to longifolene

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC1NP00006C

Titanocene-catalyzed cascade cyclization of epoxypolyprenes: straightforward synthesis of terpenoids by free-radical chemistry

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC1NP00006C

Theozymes and compuzymes: theoretical models for biological catalysis

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC1NP00006C

21 January 2018

QM/MM studies of enzymes

1 reference

https://api.crossref.org/works/10.1039%2FC1NP00006C

On possible pitfalls in ab initio quantum mechanics/molecular mechanics minimization approaches for studies of enzymatic reactions

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC1NP00006C

Proton sandwiches: nonclassical carbocations with tetracoordinate protons

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC1NP00006C

Nonclassical carbocations as C-H hydrogen bond donors

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC1NP00006C

Formation of beyerene, kaurene, trachylobane, and atiserene diterpenes by rearrangements that avoid secondary carbocations

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC1NP00006C

Tetracoordinate carbon as a nucleophile? Interconversion of carbenium ions with carbonium ions possessing nearly square-pyramidal pentacoordinate carbons.

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC1NP00006C

Concomitant C-ring Expansion and D-ring formation in lanosterol biosynthesis from squalene without violation of Markovnikov's rule

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC1NP00006C

Thermochemical and kinetic study of the carbocation ring contraction of cyclohexylium to methylcyclopentylium

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC1NP00006C

Challenges posed to bornyl diphosphate synthase: diverging reaction mechanisms in monoterpenes

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC1NP00006C

Mechanistic insights into triterpene synthesis from quantum mechanical calculations. Detection of systematic errors in B3LYP cyclization energies

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC1NP00006C

A potential energy surface bifurcation in terpene biosynthesis

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC1NP00006C

Quantum chemical dissection of the classic terpinyl/pinyl/bornyl/camphyl cation conundrum-the role of pyrophosphate in manipulating pathways to monoterpenes

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC1NP00006C

Biogenesis of sesquiterpene lactones pseudoguaianolides from germacranolides: theoretical study on the reaction mechanism of terminal biogenesis of 8-epiconfertin

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC1NP00006C

Perturbing the structure of the 2-norbornyl cation through C-H...N and C-H...pi interactions

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC1NP00006C

Balancing Kinetic and Thermodynamic Control: the Mechanism of Carbocation Cyclization by Squalene Cyclase

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC1NP00006C

Synthetic efficiency in enzyme mechanisms involving carbocations: aristolochene synthase

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC1NP00006C

Isotopically sensitive branching in the formation of cyclic monoterpenes: proof that (-)-alpha-pinene and (-)-beta-pinene are synthesized by the same monoterpene cyclase via deprotonation of a common intermediate

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC1NP00006C

Monoterpene biosynthesis: isotope effects associated with bicyclic olefin formation catalyzed by pinene synthases from sage (Salvia officinalis)

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC1NP00006C

Bornyl diphosphate synthase: structure and strategy for carbocation manipulation by a terpenoid cyclase

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC1NP00006C

16-Aza-ent-beyerane and 16-Aza-ent-trachylobane: potent mechanism-based inhibitors of recombinant ent-kaurene synthase from Arabidopsis thaliana

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC1NP00006C

Identifying and manipulating structural determinates linking catalytic specificities in terpene synthases

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC1NP00006C

X-ray Crystal Structure of Aristolochene Synthase from Aspergillus terreus and Evolution of Templates for the Cyclization of Farnesyl Diphosphate † , ‡

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC1NP00006C

Alternative termination chemistries utilized by monoterpene cyclases: chimeric analysis of bornyl diphosphate, 1,8-cineole, and sabinene synthases

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC1NP00006C

Quantitative exploration of the catalytic landscape separating divergent plant sesquiterpene synthases

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC1NP00006C

Stereochemistry of eudesmane cation formation during catalysis by aristolochene synthase from Penicillium roqueforti

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC1NP00006C

Amorpha-4,11-diene synthase: mechanism and stereochemistry of the enzymatic cyclization of farnesyl diphosphate

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC1NP00006C

Computational studies on biosynthetic carbocation rearrangements leading to sativene, cyclosativene, alpha-ylangene, and beta-ylangene

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC1NP00006C

Alteration of product formation by directed mutagenesis and truncation of the multiple-product sesquiterpene synthases delta-selinene synthase and gamma-humulene synthase

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC1NP00006C

Sesquiterpene synthases from grand fir (Abies grandis). Comparison of constitutive and wound-induced activities, and cDNA isolation, characterization, and bacterial expression of delta-selinene synthase and gamma-humulene synthase

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC1NP00006C

The carbocation continuum in terpene biosynthesis--where are the secondary cations?

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC1NP00006C

Theoretical studies on farnesyl cation cyclization: pathways to pentalenene

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC1NP00006C

Crystal structure of pentalenene synthase: mechanistic insights on terpenoid cyclization reactions in biology

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC1NP00006C

Pentalenene synthase. Analysis of active site residues by site-directed mutagenesis

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC1NP00006C

Biosynthesis of the sesquiterpene botrydial in Botrytis cinerea. Mechanism and stereochemistry of the enzymatic formation of presilphiperfolan-8beta-ol

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC1NP00006C

Modes of inactivation of trichodiene synthase by a cyclopropane-containing farnesyldiphosphate analog

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC1NP00006C

Role of arginine-304 in the diphosphate-triggered active site closure mechanism of trichodiene synthase

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC1NP00006C

X-ray crystal structures of D100E trichodiene synthase and its pyrophosphate complex reveal the basis for terpene product diversity

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC1NP00006C

Structure of trichodiene synthase from Fusarium sporotrichioides provides mechanistic inferences on the terpene cyclization cascade

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC1NP00006C

Sesquiterpenes from Cupressus macrocarpa foliage

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC1NP00006C

Consequences of conformational preorganization in sesquiterpene biosynthesis: theoretical studies on the formation of the bisabolene, curcumene, acoradiene, zizaene, cedrene, duprezianene, and sesquithuriferol sesquiterpenes

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC1NP00006C

Structural Elucidation of Cisoid and Transoid Cyclization Pathways of a Sesquiterpene Synthase Using 2-Fluorofarnesyl Diphosphates

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC1NP00006C

New pathways in transannular cyclization of germacrone [germacra-1(10),4,7(11)-trien-8-one]: evidence regarding a concerted mechanism.

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC1NP00006C

Intramolecular proton transfer in the cyclization of geranylgeranyl diphosphate to the taxadiene precursor of taxol catalyzed by recombinant taxadiene synthase

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC1NP00006C

A promiscuous proton in taxadiene biosynthesis?

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC1NP00006C

Proposed mechanism for diterpene synthases in the formation of phomactatriene and taxadiene.

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC1NP00006C

Taxadiene synthase structure and evolution of modular architecture in terpene biosynthesis

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC1NP00006C

Following evolution's lead to a single residue switch for diterpene synthase product outcome.

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC1NP00006C

Enzymatic cyclization of squalene and oxidosqualene to sterols and triterpenes

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC1NP00006C

Rearrangement pathways of five-membered ring enlargement in carbocations: quantum chemical calculations and deuterium kinetic isotope effects.

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC1NP00006C

Conformational energetics of cationic backbone rearrangements in triterpenoid biosynthesis provide an insight into enzymatic control of product

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC1NP00006C

Structure and reactivity of the dammarenyl cation: configurational transmission in triterpene synthesis

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC1NP00006C

An Arabidopsis oxidosqualene cyclase catalyzes iridal skeleton formation by Grob fragmentation

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC1NP00006C

Conversion of squalene to the pentacarbocyclic hopene

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC1NP00006C

Cationic cyclopropanation by antibody catalysis

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC1NP00006C

The energy of the transition states and the intermediate cation in the ionization of 2-norbornyl derivatives. Where is the nonclassical stabilization energy?

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC1NP00006C

Conclusion of the classical-nonclassical ion controversy based on the structural study of the 2-norbornyl cation

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC1NP00006C

An innocent bystander looks at the 2-norbornyl cation

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC1NP00006C

The Cationminus signpi Interaction

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC1NP00006C

The aromatic sidechains of amino acids as neutral donor groups for alkali metal cations

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC1NP00006C

Many Density Functional Theory Approaches Fail To Give Reliable Large Hydrocarbon Isomer Energy Differences

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC1NP00006C

Theoretical studies on farnesyl transferase: Evidence for thioether product coordination to the active-site zinc sphere

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC1NP00006C

Theoretical studies on farnesyltransferase: The distances paradox explained

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC1NP00006C