(Q38029252)

https://www.ebi.ac.uk/europepmc/webservices/rest/search?query=EXT_ID:22828928%20AND%20SRC:MED&resulttype=core&format=json

8 February 2020

title

Insights into the elementary steps in Negishi coupling through kinetic investigations (English)

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8 February 2020

2

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8 February 2020

author name string

Liqun Jin

series ordinal

1

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8 February 2020

publication date

25 July 2012

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https://www.ebi.ac.uk/europepmc/webservices/rest/search?query=EXT_ID:22828928%20AND%20SRC:MED&resulttype=core&format=json

Organic and Biomolecular Chemistry

8 February 2020

published in

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8 February 2020

volume

10

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8 February 2020

issue

34

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8 February 2020

page(s)

6817-6825

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Highly general stereo-, regio-, and chemo-selective synthesis of terminal and internal conjugated enynes by the Pd-catalysed reaction of alkynylzinc reagents with alkenyl halides

8 February 2020

cites work

1 reference

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Selective carbon-carbon bond formation via transition metal catalysis. 3. A highly selective synthesis of unsymmetrical biaryls and diarylmethanes by the nickel- or palladium-catalyzed reaction of aryl- and benzylzinc derivatives with aryl halides

21 January 2018

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Palladium-catalyzed cross-coupling reactions in total synthesis

21 January 2018

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Advances in transition metal (Pd, Ni, Fe)-catalyzed cross-coupling reactions using alkyl-organometallics as reaction partners

21 January 2018

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Nickel-catalysed Negishi cross-coupling reactions: scope and mechanisms

21 January 2018

1 reference

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A user-friendly, all-purpose Pd-NHC (NHC=N-heterocyclic carbene) precatalyst for the negishi reaction: a step towards a universal cross-coupling catalyst

21 January 2018

1 reference

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Room-temperature Negishi cross-coupling of unactivated alkyl bromides with alkyl organozinc reagents utilizing a Pd/N-heterocyclic carbene catalyst

21 January 2018

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The first Negishi cross-coupling reaction of two alkyl centers utilizing a Pd-N-heterocyclic carbene (NHC) catalyst

21 January 2018

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The first general method for palladium-catalyzed Negishi cross-coupling of aryl and vinyl chlorides: use of commercially available Pd(P(t-Bu)(3))(2) as a catalyst.

21 January 2018

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Nickel-catalyzed asymmetric cross-couplings of racemic propargylic halides with arylzinc reagents

21 January 2018

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Palladium-catalyzed negishi cross-coupling reactions of unactivated alkyl iodides, bromides, chlorides, and tosylates

21 January 2018

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Exposing the hidden complexity of stoichiometric and catalytic metathesis reactions by elucidation of Mg-Zn hybrids

21 January 2018

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Identification of a higher-order organozincate intermediate involved in Negishi cross-coupling reactions by mass spectrometry and NMR spectroscopy.

21 January 2018

1 reference

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What is the rate of the Csp2-Csp2 reductive elimination step? Revealing an unusually fast Ni-catalyzed Negishi-type oxidative coupling reaction.

21 January 2018

1 reference

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Ligand effects on Negishi couplings of alkenyl halides

21 January 2018

1 reference

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Density functional theory studies of negishi alkyl-alkyl cross-coupling reactions catalyzed by a methylterpyridyl-Ni(I) complex

21 January 2018

1 reference

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Identification of a highly efficient alkylated pincer thioimido-palladium(II) complex as the active catalyst in Negishi coupling

21 January 2018

1 reference

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Revealing a second transmetalation step in the Negishi coupling and its competition with reductive elimination: improvement in the interpretation of the mechanism of biaryl syntheses.

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC2OB25650A

Insights into the mechanism of the Negishi reaction: ZnRX versus ZnR2 reagents

21 January 2018

1 reference

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Mechanism of aryl chloride amination: base-induced oxidative addition

21 January 2018

1 reference

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Oxidative addition of aryl tosylates to palladium(0) and coupling of unactivated aryl tosylates at room temperature

21 January 2018

1 reference

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Distinct mechanisms for the oxidative addition of chloro-, bromo-, and iodoarenes to a bisphosphine palladium(0) complex with hindered ligands

21 January 2018

1 reference

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Effect of ligand steric properties and halide identity on the mechanism for oxidative addition of haloarenes to trialkylphosphine Pd(0) complexes

21 January 2018

1 reference

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On the Configuration Resulting from Oxidative Addition of RX to Pd(PPh 3 ) 4 and the Mechanism of the cis -to- trans Isomerization of [PdRX(PPh 3 ) 2 ] Complexes (R = Aryl, X = Halide) †

21 January 2018

1 reference

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Alkylboranes in the Suzuki-Miyaura Coupling: Stereochemical and Mechanistic Studies

21 January 2018

1 reference

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Transmetalation of Alkylboranes to Palladium in the Suzuki Coupling Reaction Proceeds with Retention of Stereochemistry

21 January 2018

1 reference

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Palladium-catalyzed coupling of tetraorganotin compounds with aryl and benzyl halides. Synthetic utility and mechanism

21 January 2018

1 reference

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Mechanism of the Stille reaction catalyzed by palladium ligated to arsine ligand: PhPdI(AsPh3)(DMF) is the species reacting with vinylstannane in DMF.

21 January 2018

1 reference

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Mechanism of the Stille Reaction. 2. Couplings of Aryl Triflates with Vinyltributyltin. Observation of Intermediates. A More Comprehensive Scheme

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC2OB25650A

Analysis of key steps in the catalytic cross-coupling of alkyl electrophiles under Negishi-like conditions

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC2OB25650A

Palladium Round Trip in the Negishi Coupling of trans-[PdMeCl(PMePh2)2] with ZnMeCl: An Experimental and DFT Study of the Transmetalation Step

21 January 2018

1 reference

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Pincer thioamide and pincer thioimide palladium complexes catalyze highly efficient Negishi coupling of primary and secondary alkyl zinc reagents at room temperature

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC2OB25650A

Acceleration of reductive elimination of [Ar-Pd-C(sp3)] by a phosphine/electron-deficient olefin ligand: a kinetic investigation

21 January 2018

1 reference

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Anionic Pd(0) and Pd(II) Intermediates in Palladium-Catalyzed Heck and Cross-Coupling Reactions

21 January 2018

1 reference

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Mechanisms of 1,1-reductive elimination from palladium

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC2OB25650A

One-pot Negishi cross-coupling reactions of in situ generated zinc reagents with aryl chlorides, bromides, and triflates

21 January 2018

1 reference

https://api.crossref.org/works/10.1039%2FC2OB25650A

Aggregation and Reactivity of Organozincate Anions Probed by Electrospray Mass Spectrometry

21 January 2018

1 reference

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Role and effects of halide ions on the rates and mechanisms of oxidative addition of iodobenzene to low-ligated zerovalent palladium complexes Pd0(PPh3)2

21 January 2018

1 reference

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Evidence for the Ligation of Palladium(0) Complexes by Acetate Ions: Consequences on the Mechanism of Their Oxidative Addition with Phenyl Iodide and PhPd(OAc)(PPh3)2 as Intermediate in the Heck Reaction

21 January 2018

1 reference

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Transmetallation Reactions Involving Group 10 Metals

21 January 2018

1 reference

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21 January 2018

Identifiers

DOI

10.1039/C2OB25650A

1 reference

https://www.ebi.ac.uk/europepmc/webservices/rest/search?query=EXT_ID:22828928%20AND%20SRC:MED&resulttype=core&format=json

8 February 2020

1 reference