(Q38150993)

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Mechanistic aspects of dinitrogen cleavage and hydrogenation to produce ammonia in catalysis and organometallic chemistry: relevance of metal hydride bonds and dihydrogen.

scientific article published on January 2014

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27 February 2020

Mechanistic aspects of dinitrogen cleavage and hydrogenation to produce ammonia in catalysis and organometallic chemistry: relevance of metal hydride bonds and dihydrogen (English)

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Europe PubMed Central

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27 February 2020

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Elsje Alessandra Quadrelli

2

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27 February 2020

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Hong-Peng Jia

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27 February 2020

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1 January 2014

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27 February 2020

Chemical Society Reviews

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27 February 2020

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27 February 2020

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27 February 2020

547-564

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27 February 2020

Catalytic reduction of molecular nitrogen in solutions

1 reference

https://api.crossref.org/works/10.1039%2FC3CS60206K

21 January 2018

Structural Basis of Biological Nitrogen Fixation.

1 reference

https://api.crossref.org/works/10.1039%2FC3CS60206K

21 January 2018

Mechanism of Molybdenum Nitrogenase

1 reference

https://api.crossref.org/works/10.1039%2FC3CS60206K

21 January 2018

Climbing nitrogenase: toward a mechanism of enzymatic nitrogen fixation

1 reference

https://api.crossref.org/works/10.1039%2FC3CS60206K

21 January 2018

Nitrogenase: a draft mechanism

1 reference

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21 January 2018

Reactions at surfaces: from atoms to complexity (Nobel Lecture).

1 reference

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21 January 2018

Detonator of the population explosion

1 reference

https://api.crossref.org/works/10.1039%2FC3CS60206K

21 January 2018

Catalytic reduction of dinitrogen to ammonia at a single molybdenum center

1 reference

https://api.crossref.org/works/10.1039%2FC3CS60206K

21 January 2018

A molybdenum complex bearing PNP-type pincer ligands leads to the catalytic reduction of dinitrogen into ammonia

1 reference

https://api.crossref.org/works/10.1039%2FC3CS60206K

21 January 2018

Energetics and mechanism of ammonia synthesis through the Chatt Cycle: conditions for a catalytic mode and comparison with the Schrock Cycle.

1 reference

https://api.crossref.org/works/10.1039%2FC3CS60206K

21 January 2018

Theoretical, spectroscopic, and mechanistic studies on transition-metal dinitrogen complexes: implications to reactivity and relevance to the nitrogenase problem

1 reference

https://api.crossref.org/works/10.1039%2FC3CS60206K

21 January 2018

Recent advances in the chemistry of nitrogen fixation

1 reference

https://api.crossref.org/works/10.1039%2FC3CS60206K

21 January 2018

Dinitrogen cleavage and functionalization by carbon monoxide promoted by a hafnium complex

1 reference

https://api.crossref.org/works/10.1039%2FC3CS60206K

21 January 2018

Side-on end-on bound dinitrogen: an activated bonding mode that facilitates functionalizing molecular nitrogen.

1 reference

https://api.crossref.org/works/10.1039%2FC3CS60206K

21 January 2018

Catalytic reduction of dinitrogen to ammonia by molybdenum: theory versus experiment

1 reference

https://api.crossref.org/works/10.1039%2FC3CS60206K

21 January 2018

Dinitrogen Cleavage by a Three-Coordinate Molybdenum(III) Complex

1 reference

https://api.crossref.org/works/10.1039%2FC3CS60206K

21 January 2018

First-principles investigation of the Schrock mechanism of dinitrogen reduction employing the full HIPTN3N ligand

1 reference

https://api.crossref.org/works/10.1039%2FC3CS60206K

21 January 2018

Triggering N(2) uptake via redox-induced expulsion of coordinated NH(3) and N(2) silylation at trigonal bipyramidal iron.

1 reference

https://api.crossref.org/works/10.1039%2FC3CS60206K

21 January 2018

Recent developments in the homogeneous reduction of dinitrogen by molybdenum and iron

1 reference

https://api.crossref.org/works/10.1039%2FC3CS60206K

21 January 2018

Coordination of a Complete Series of N2Reduction Intermediates (N2H2, N2H4, and NH3) to an Iron Phosphine Scaffold

1 reference

https://api.crossref.org/works/10.1039%2FC3CS60206K

21 January 2018

Hydrogenation and cleavage of dinitrogen to ammonia with a zirconium complex

1 reference

https://api.crossref.org/works/10.1039%2FC3CS60206K

21 January 2018

Catalytic Synthesis of Ammonia—A “Never‐Ending Story”?

1 reference

https://api.crossref.org/works/10.1039%2FC3CS60206K

21 January 2018

Impact of surface chemistry

1 reference

https://api.crossref.org/works/10.1039%2FC3CS60206K

21 January 2018

Ammonia synthesis from first-principles calculations.

1 reference

https://api.crossref.org/works/10.1039%2FC3CS60206K

21 January 2018

Predicting catalysis: understanding ammonia synthesis from first-principles calculations

1 reference

https://api.crossref.org/works/10.1039%2FC3CS60206K

21 January 2018

Fundamentals of H2 binding and reactivity on transition metals underlying hydrogenase function and H2 production and storage

1 reference

https://api.crossref.org/works/10.1039%2FC3CS60206K

21 January 2018

Dinitrogen dissociation on an isolated surface tantalum atom

1 reference

https://api.crossref.org/works/10.1039%2FC3CS60206K

21 January 2018

H/D Exchange on Silica-Grafted Tantalum(V) Imido Amido [(≡SiO)2Ta(V)(NH)(NH2)] Synthesized from Either Ammonia or Dinitrogen: IR and DFT Evidence for Heterolytic Splitting of D2

1 reference

https://api.crossref.org/works/10.1039%2FC3CS60206K

21 January 2018

Energetics and mechanism of dinitrogen cleavage at a mononuclear surface tantalum center: a new way of dinitrogen reduction

1 reference

https://api.crossref.org/works/10.1039%2FC3CS60206K

21 January 2018

Successive heterolytic cleavages of H2 achieve N2 splitting on silica-supported tantalum hydrides: a DFT proposed mechanism.

1 reference

https://api.crossref.org/works/10.1039%2FC3CS60206K

21 January 2018

Proton-coupled electron transfer

1 reference

https://api.crossref.org/works/10.1039%2FC3CS60206K

21 January 2018

Heterolytic cleavage of ammonia N–H bond by bifunctional activation in silica-grafted single site Ta(V) imido amido surface complex. Importance of the outer sphere NH3 assistance

1 reference

https://api.crossref.org/works/10.1039%2FC3CS60206K

21 January 2018

Nitrogenase MoFe-protein at 1.16 A resolution: a central ligand in the FeMo-cofactor

1 reference

https://api.crossref.org/works/10.1039%2FC3CS60206K

21 January 2018

Evidence for Interstitial Carbon in Nitrogenase FeMo Cofactor

1 reference

https://api.crossref.org/works/10.1039%2FC3CS60206K

21 January 2018

X-ray emission spectroscopy evidences a central carbon in the nitrogenase iron-molybdenum cofactor

1 reference

https://api.crossref.org/works/10.1039%2FC3CS60206K

21 January 2018

Radical SAM-dependent carbon insertion into the nitrogenase M-cluster

1 reference

https://api.crossref.org/works/10.1039%2FC3CS60206K

21 January 2018

Ammonia formation by a thiolate-bridged diiron amide complex as a nitrogenase mimic

1 reference

https://api.crossref.org/works/10.1039%2FC3CS60206K

21 January 2018

The mechanism of Klebsiella pneumoniae nitrogenase action. Pre-steady-state kinetics of an enzyme-bound intermediate in N2 reduction and of NH3 formation

1 reference

https://api.crossref.org/works/10.1039%2FC3CS60206K

21 January 2018

Unification of reaction pathway and kinetic scheme for N2 reduction catalyzed by nitrogenase

1 reference

https://api.crossref.org/works/10.1039%2FC3CS60206K

21 January 2018

Formation of Ammonia in the Reactions of a Tungsten Dinitrogen with Ruthenium Dihydrogen Complexes under Mild Reaction Conditions1

1 reference

https://api.crossref.org/works/10.1039%2FC3CS60206K

21 January 2018

Well-defined surface imido amido tantalum(v) species from ammonia and silica-supported tantalum hydrides

1 reference

https://api.crossref.org/works/10.1039%2FC3CS60206K

21 January 2018

Identifiers

10.1039/C3CS60206K

1 reference

Europe PubMed Central

PubMed publication ID

https://www.ebi.ac.uk/europepmc/webservices/rest/search?query=EXT_ID:24108246%20AND%20SRC:MED&resulttype=core&format=json

27 February 2020

PubMed publication ID

1 reference

Europe PubMed Central

PubMed publication ID

https://www.ebi.ac.uk/europepmc/webservices/rest/search?query=EXT_ID:24108246%20AND%20SRC:MED&resulttype=core&format=json

27 February 2020

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