(Q53086192)

11 May 2018

title

There is no universal mechanism for the cleavage of RNA model compounds in the presence of metal ion catalysts. (English)

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11 May 2018

author name string

Heidi Korhonen

1

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11 May 2018

Timo Koivusalo

2

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11 May 2018

Suvi Toivola

3

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11 May 2018

Satu Mikkola

4

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11 May 2018

publication date

18 October 2013

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11 May 2018

Organic and Biomolecular Chemistry

published in

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11 May 2018

volume

11

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issue

48

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11 May 2018

page(s)

8324-8339

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11 May 2018

Mode of action of bi- and trinuclear zinc hydrolases and their synthetic analogues

cites work

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21 January 2018

Artificial ribonucleases

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Phosphate binding energy and catalysis by small and large molecules

21 January 2018

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Cleavage of RNA phosphodiester bonds by small molecular entities: a mechanistic insight.

21 January 2018

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Compelling evidence for a stepwise mechanism of the alkaline cyclisation of uridine 3'-phosphate esters

21 January 2018

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Cooperativity between metal ions in the cleavage of phosphate diesters and RNA by dinuclear Zn(II) catalysts

21 January 2018

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Combination of a dinuclear Zn2+ complex and a medium effect exerts a 10(12)-fold rate enhancement of cleavage of an RNA and DNA model system.

21 January 2018

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Cleavage and isomerization of UpU promoted by dinuclear metal ion complexes.

21 January 2018

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Substrate specificity of an active dinuclear Zn(II) catalyst for cleavage of RNA analogues and a dinucleoside

21 January 2018

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Solvent deuterium isotope effects on phosphodiester cleavage catalyzed by an extraordinarily active Zn(II) complex

21 January 2018

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Structural, kinetic, and theoretical studies on models of the zinc-containing phosphodiesterase active center: medium-dependent reaction mechanisms.

21 January 2018

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Dinuclear Zn(II) complex catalyzed phosphodiester cleavage proceeds via a concerted mechanism: a density functional theory study.

21 January 2018

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The mechanism of the metal ion promoted cleavage of RNA phosphodiester bonds involves a general acid catalysis by the metal aquo ion on the departure of the leaving group

21 January 2018

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The ligand effect on the hydrolytic reactivity of Zn(II) complexes toward phosphate diesters

21 January 2018

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Physical and kinetic analysis of the cooperative role of metal ions in catalysis of phosphodiester cleavage by a dinuclear Zn(II) complex

21 January 2018

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Investigation of the effect of oxy bridging groups in dinuclear Zn(II) complexes that catalyze the cleavage of a simple phosphate diester RNA analogue

21 January 2018

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Dinuclear Zn2+ complexes in the hydrolysis of the phosphodiester linkage in a diribonucleoside monophosphate diester.

21 January 2018

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Molecular design of an acid-base cooperative catalyst for RNA cleavage based on a dizinc complex

21 January 2018

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A transition state analog for phosphate diester cleavage catalyzed by a small enzyme-like metal ion complex.

21 January 2018

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Altered transition state for the reaction of an RNA model catalyzed by a dinuclear zinc(II) catalyst

21 January 2018

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1,4,7,10-tetraazacyclododecane metal complexes as potent promoters of phosphodiester hydrolysis under physiological conditions

21 January 2018

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A DFT study on the mechanism of phosphodiester cleavage mediated by monozinc complexes.

21 January 2018

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A minimalist approach to understanding the efficiency of mononuclear Zn(ii) complexes as catalysts of cleavage of an RNA analog

21 January 2018

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Structural characterization of a dizinc(ii) complex with bridging η2-phosphate diesters and internal N–H⋯O–P hydrogen bonding

21 January 2018

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βLGvalues in mechanistic studies on the transesterification of RNA models and their application in a metal ion complex promoted transesterification

21 January 2018

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Efficient Phosphodiester Binding and Cleavage by a ZnII Complex Combining Hydrogen-Bonding Interactions and Double Lewis Acid Activation

21 January 2018

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Comparing a mononuclear Zn(ii) complex with hydrogen bond donors with a dinuclear Zn(ii) complex for catalysing phosphate ester cleavage

21 January 2018

1 reference

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The Mechanism of Cleavage and Isomerisation of RNA Promoted by an Efficient Dinuclear Zn2+ Complex

21 January 2018

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https://api.crossref.org/works/10.1039%2FC3OB41554F

21 January 2018

Identifiers

DOI

10.1039/C3OB41554F

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11 May 2018

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11 May 2018