(Q26747304)

title

Dynamic behavior of rearranging carbocations - implications for terpene biosynthesis (English)

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1

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9 June 2020

Dean J Tantillo

series ordinal

2

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Beilstein Journal of Organic Chemistry

9 June 2020

author name string

Stephanie R Hare

series ordinal

1

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Dean J Tantillo

series ordinal

2

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language of work or name

English

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publication date

2016

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published in

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9 June 2020

volume

12

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https://www.ebi.ac.uk/europepmc/webservices/rest/search?query=EXT_ID:27340434%20AND%20SRC:MED&resulttype=core&format=json

9 June 2020

page(s)

377-390

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Biosynthesis of the sesquiterpene antibiotic albaflavenone in Streptomyces coelicolor A3(2)

9 June 2020

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28 September 2017

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28 September 2017

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28 September 2017

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Computational analysis of the mechanism of chemical reactions in terms of reaction phases: hidden intermediates and hidden transition States

28 September 2017

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A functional genomics approach to tanshinone biosynthesis provides stereochemical insights.

28 September 2017

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28 September 2017

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Unearthing the roots of the terpenome

28 September 2017

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28 September 2017

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Structural biology and chemistry of the terpenoid cyclases

28 September 2017

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Genome mining in Streptomyces coelicolor: molecular cloning and characterization of a new sesquiterpene synthase

28 September 2017

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Nonstatistical dynamics in thermal reactions of polyatomic molecules

28 September 2017

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28 September 2017

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Diterpenoid resin acid biosynthesis in conifers: characterization of two cytochrome P450-dependent monooxygenases and an aldehyde dehydrogenase involved in abietic acid biosynthesis

28 September 2017

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Diterpenoid resin acid biosynthesis in conifers: enzymatic cyclization of geranylgeranyl pyrophosphate to abietadiene, the precursor of abietic acid

28 September 2017

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28 September 2017

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31 May 2018

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31 May 2018

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28 November 2018

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Gas-Phase Chemical Dynamics Simulations on the Bifurcating Pathway of the Pimaradienyl Cation Rearrangement: Role of Enzymatic Steering in Abietic Acid Biosynthesis

28 November 2018

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28 November 2018

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28 November 2018

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28 November 2018

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Analogies between synthetic and biosynthetic reactions in which [1,2]-alkyl shifts are combined with other events: dyotropic, Schmidt, and carbocation rearrangements

28 November 2018

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Quantum chemical dissection of the classic terpinyl/pinyl/bornyl/camphyl cation conundrum-the role of pyrophosphate in manipulating pathways to monoterpenes

28 November 2018

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Challenges posed to bornyl diphosphate synthase: diverging reaction mechanisms in monoterpenes

28 November 2018

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Formation of beyerene, kaurene, trachylobane, and atiserene diterpenes by rearrangements that avoid secondary carbocations

28 November 2018

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Mechanism of alkane dehydrogenation catalyzed by acidic zeolites: Ab initio transition path sampling

28 November 2018

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Consequences of conformational preorganization in sesquiterpene biosynthesis: theoretical studies on the formation of the bisabolene, curcumene, acoradiene, zizaene, cedrene, duprezianene, and sesquithuriferol sesquiterpenes

28 November 2018

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Biosynthesis of the sesquiterpene antibiotic albaflavenone in Streptomyces coelicolor. Mechanism and stereochemistry of the enzymatic formation of epi-isozizaene

28 November 2018

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Computational studies on biosynthetic carbocation rearrangements leading to sativene, cyclosativene, alpha-ylangene, and beta-ylangene

28 November 2018

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Stereochemistry of the cyclization-rearrangement of (+)-copalyl diphosphate to (-)-abietadiene catalyzed by recombinant abietadiene synthase from Abies grandis

28 November 2018

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12 December 2020

A SN2 reaction that avoids its deep potential energy minimum

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12 December 2020

Dynamics-driven reaction pathway in an intramolecular rearrangement

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12 December 2020

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Carbocation Branching Observed in a Simulation

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12 December 2020

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12 December 2020

How many secondary carbocations are involved in the biosynthesis of avermitilol?

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The need for enzymatic steering in abietic acid biosynthesis: gas-phase chemical dynamics simulations of carbocation rearrangements on a bifurcating potential energy surface

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12 December 2020

Electrostatically Guided Dynamics—The Root of Fidelity in a Promiscuous Terpene Synthase?

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12 December 2020

Biosynthetic consequences of multiple sequential post-transition-state bifurcations

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12 December 2020

Dynamic effects dictate the mechanism and selectivity of dehydration-rearrangement reactions of protonated alcohols [Me2 (R)CCH(OH2 )Me](+) (R=Me, Et, iPr) in the gas phase

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The 9-homocubyl cation rearrangement revisited

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Unravelling the scent of vetiver: identification of character-impact compounds

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The Carbocation Rearrangement Mechanism, Clarified

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12 December 2020

Modulation of inherent dynamical tendencies of the bisabolyl cation via preorganization in epi-isozizaene synthase

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12 December 2020

Computational Organic Chemistry

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Cyclization Enzymes in the Biosynthesis of Monoterpenes, Sesquiterpenes, and Diterpenes

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Development of transition-state theory

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7 January 2021

Isotopic perturbation of degeneracy. Carbon-13 nuclear magnetic resonance spectra of dimethylcyclopentyl and dimethylnorbornyl cations

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7 January 2021

Isotopic perturbation of resonance. Carbon-13 nuclear magnetic resonance spectra of deuterated cyclohexenyl and cyclopentenyl cations

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7 January 2021

1,5 PARTICIPATION IN THE SOLVOLYSIS OF β-(Δ3-CYCLOPENTENYL)-ETHYL p-NITROBENZENESULFONATE

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7 January 2021

Current Status of Transition-State Theory

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Self‐Consistent Molecular‐Orbital Methods. IX. An Extended Gaussian‐Type Basis for Molecular‐Orbital Studies of Organic Molecules

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The Activated Complex in Chemical Reactions

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On the structure and dynamics of secondary n-alkyl cations

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A new mixing of Hartree–Fock and local density‐functional theories

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Density-functional thermochemistry. III. The role of exact exchange

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Identifiers

DOI

10.3762/BJOC.12.41

1 reference

https://www.ebi.ac.uk/europepmc/webservices/rest/search?query=EXT_ID:27340434%20AND%20SRC:MED&resulttype=core&format=json

9 June 2020

1 reference

https://www.ebi.ac.uk/europepmc/webservices/rest/search?query=EXT_ID:27340434%20AND%20SRC:MED&resulttype=core&format=json

9 June 2020

PubMed publication ID

27340434

1 reference

https://www.ebi.ac.uk/europepmc/webservices/rest/search?query=EXT_ID:27340434%20AND%20SRC:MED&resulttype=core&format=json