(Q33393660)

26 July 2017

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title

Small molecule mimics of hydrogenases: hydrides and redox (English)

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26 July 2017

Frédéric Gloaguen

1

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author name string

Thomas B Rauchfuss

series ordinal

2

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26 July 2017

language of work or name

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31 October 2008

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26 July 2017

published in

Chemical Society Reviews

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26 July 2017

volume

38

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26 July 2017

issue

1

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26 July 2017

page(s)

100-108

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Nitrosyl derivatives of diiron(I) dithiolates mimic the structure and Lewis acidity of the [FeFe]-hydrogenase active site.

26 July 2017

cites work

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3462221

The crystal structure of [Fe]-hydrogenase reveals the geometry of the active site

21 June 2018

1 reference

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Redox and structural properties of mixed-valence models for the active site of the [FeFe]-hydrogenase: progress and challenges

21 June 2018

1 reference

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Desymmetrized Diiron Azadithiolato Carbonyls: A Step Toward Modeling the Iron-Only Hydrogenases

21 June 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3462221

Thiolate-bridged dinuclear iron(tris-carbonyl)-nickel complexes relevant to the active site of [NiFe] hydrogenase

21 June 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3462221

Diiron dithiolato carbonyls related to the H(ox)CO state of [FeFe]-hydrogenase.

21 June 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3462221

Terminal hydride in [FeFe]-hydrogenase model has lower potential for H2 production than the isomeric bridging hydride

21 June 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3462221

Visible light-driven electron transfer and hydrogen generation catalyzed by bioinspired [2Fe2S] complexes.

21 June 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3462221

Dithiomethylether as a ligand in the hydrogenase h-cluster

21 June 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3462221

Computational studies of [NiFe] and [FeFe] hydrogenases.

21 June 2018

1 reference

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Structure/Function Relationships of [NiFe]- and [FeFe]-Hydrogenases

21 June 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3462221

Unsaturated, mixed-valence diiron dithiolate model for the H(ox) state of the [FeFe] hydrogenase

21 June 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3462221

Electrocatalytic hydrogen evolution at low overpotentials by cobalt macrocyclic glyoxime and tetraimine complexes

21 June 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3462221

A dinuclear Ni(mu-H)Ru complex derived from H2.

21 June 2018

1 reference

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Evidence for the formation of terminal hydrides by protonation of an asymmetric iron hydrogenase active site mimic

21 June 2018

1 reference

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Synthesis of the H-cluster framework of iron-only hydrogenase.

21 June 2018

1 reference

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Electrocatalytic proton reduction by phosphido-bridged diiron carbonyl compounds: distant relations to the H-cluster?

21 June 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3462221

Chemistry and the hydrogenases.

21 June 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3462221

Synthetic and structural studies on [Fe2(SR)2(CN)x(CO)6-x](x-) as active site models for Fe-only hydrogenases.

21 June 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3462221

H/D exchange reactions in dinuclear iron thiolates as activity assay models of Fe-H2ase

21 June 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3462221

Isolation and first EPR characterization of the [FeFe]-hydrogenases from green algae.

21 June 2018

1 reference

Transient FTIR spectroelectrochemical and stopped-flow detection of a mixed valence (Fe(I)-Fe(II)) bridging carbonyl intermediate with structural elements and spectroscopic characteristics of the di-iron sub-site of all-iron hydrogenase.

21 January 2018

1 reference

Activation of alkenes and H2 by [Fe]-H2ase model complexes

21 January 2018

1 reference

Crystallographic and FTIR spectroscopic evidence of changes in Fe coordination upon reduction of the active site of the Fe-only hydrogenase from Desulfovibrio desulfuricans.

21 January 2018

1 reference

Pendant bases as proton relays in iron hydride and dihydrogen complexes

21 January 2018

1 reference

Hydrogen oxidation and production using nickel-based molecular catalysts with positioned proton relays.

21 January 2018

1 reference

Chemistry of ruthenium(II) and osmium(II) ammines

21 January 2018

1 reference

Preparative and structural studies on the carbonyl cyanides of iron, manganese, and ruthenium: fundamentals relevant to the hydrogenases.

21 January 2018

1 reference

Hydrogen generation from weak acids: electrochemical and computational studies of a diiron hydrogenase mimic

21 January 2018

1 reference

Bimetallic carbonyl thiolates as functional models for Fe-only hydrogenases

21 January 2018

1 reference

Slow Proton-Transfer Reactions in Organometallic and Bioinorganic Chemistry

21 January 2018

1 reference

Molybdenum-sulfur dimers as electrocatalysts for the production of hydrogen at low overpotentials.

21 January 2018

1 reference

Iron-only hydrogenase mimics. Thermodynamic aspects of the use of electrochemistry to evaluate catalytic efficiency for hydrogen generation.

21 January 2018

1 reference

Biomimetic hydrogen evolution catalyzed by an iron carbonyl thiolate

21 January 2018

1 reference

12 December 2020

Protonation studies of the new iron carbonyl cyanide trans-[Fe(CO)3(CN)2]2-: implications with respect to hydrogenases

1 reference

12 December 2020

Electron transfer at a dithiolate-bridged diiron assembly: electrocatalytic hydrogen evolution

1 reference

12 December 2020

Characterization of a diferrous terminal hydride mechanistically relevant to the Fe-only hydrogenases

1 reference

12 December 2020

Mononuclear [NiII(L)(P-(o-C6H4S)2(o-C6H4SH))]0/1- (L = thiolate, selenolate, PPh3, and Cl) complexes with intramolecular [Ni...S...H...S]/[Ni...H...S] interactions modulated by the coordinated ligand L: relevance to the [NiFe] hydrogenases

1 reference

12 December 2020

Electrocatalytic production of hydrogen by a synthetic model of [NiFe] hydrogenases

1 reference

12 December 2020

Active-site models for iron hydrogenases: reduction chemistry of dinuclear iron complexes

1 reference

12 December 2020

Bio-inspired, side-on attachment of a ruthenium photosensitizer to an iron hydrogenase active site model

1 reference

12 December 2020

A Mixed-Valent, Fe(II)Fe(I), Diiron Complex Reproduces the Unique Rotated State of the [FeFe]Hydrogenase Active Site

1 reference

12 December 2020

Ligand versus metal protonation of an iron hydrogenase active site mimic

1 reference

12 December 2020

Modeling [Fe-Fe] hydrogenase: evidence for bridging carbonyl and distal iron coordination vacancy in an electrocatalytically competent proton reduction by an iron thiolate assembly that operates through Fe(0)-Fe(II) levels

1 reference

12 December 2020

Use of 1,10-phenanthroline in diiron dithiolate derivatives related to the [Fe-Fe] hydrogenase active site

1 reference

12 December 2020

On the structure of a proposed mixed-valent analogue of the diiron subsite of [FeFe]-hydrogenase

1 reference

12 December 2020

Electrochemical insights into the mechanisms of proton reduction by [Fe2(CO)6{micro-SCH2N(R)CH2S}] complexes related to the [2Fe](H) subsite of [FeFe]hydrogenase

1 reference

12 December 2020

trans-[Fe(CN)4 (CO)2 ]2- , a 21st Century [Fe(CN)(CO)] Compound

1 reference

12 December 2020

Identifiers

DOI

10.1039/B801796B

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26 July 2017

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26 July 2017

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