(Q33992789)

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Manganese catalysts for C-H activation: an experimental/theoretical study identifies the stereoelectronic factor that controls the switch between hydroxylation and desaturation pathways

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scholarly article

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Europe PubMed Central

PubMed publication ID

30 July 2017

Manganese catalysts for C-H activation: an experimental/theoretical study identifies the stereoelectronic factor that controls the switch between hydroxylation and desaturation pathways (English)

1 reference

Europe PubMed Central

PubMed publication ID

30 July 2017

Odile Eisenstein

7

1 reference

Europe PubMed Central

PubMed publication ID

30 July 2017

Christophe Raynaud

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Christophe Raynaud

4

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David Balcells

2

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5

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Gary W Brudvig

1 reference

Europe PubMed Central

PubMed publication ID

30 July 2017

author name string

Jonathan F Hull

1

1 reference

Europe PubMed Central

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30 July 2017

Effiette L O Sauer

3

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Europe PubMed Central

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30 July 2017

Robert H Crabtree

6

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Europe PubMed Central

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30 July 2017

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publication date

1 June 2010

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Europe PubMed Central

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30 July 2017

Journal of the American Chemical Society

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Europe PubMed Central

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30 July 2017

132

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Europe PubMed Central

PubMed publication ID

30 July 2017

22

1 reference

Europe PubMed Central

PubMed publication ID

30 July 2017

7605-7616

1 reference

Europe PubMed Central

PubMed publication ID

30 July 2017

Effect of porphyrin ligands on the regioselective dehydrogenation versus epoxidation of olefins by oxoiron(IV) mimics of cytochrome P450.

1 reference

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28 July 2018

A highly reactive p450 model compound I.

1 reference

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28 July 2018

Highly reactive porphyrin-iron-oxo derivatives produced by photolyses of metastable porphyrin-iron(IV) diperchlorates

1 reference

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28 July 2018

A combined NRVS and DFT study of Fe(IV)=O model complexes: a diagnostic method for the elucidation of non-heme iron enzyme intermediates

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2903729

28 July 2018

Ruthenium catalyzed biomimetic oxidation in organic synthesis inspired by cytochrome P-450.

1 reference

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28 July 2018

Substrate-dependent stereochemical course of the (Z)-13-desaturation catalyzed by the processionary moth multifunctional desaturase

1 reference

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28 July 2018

Trans-dioxo manganese(V) porphyrins

1 reference

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The road to non-heme oxoferryls and beyond

1 reference

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28 July 2018

High-valent iron(IV)-oxo complexes of heme and non-heme ligands in oxygenation reactions

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2903729

28 July 2018

Synthesis, characterization, and reactivities of manganese(V)-oxo porphyrin complexes

1 reference

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28 July 2018

Water-splitting chemistry of photosystem II.

1 reference

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28 July 2018

A single mutation in the castor Delta9-18:0-desaturase changes reaction partitioning from desaturation to oxidase chemistry

1 reference

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28 July 2018

Structure and chemistry of cytochrome P450.

1 reference

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28 July 2018

Manganese clusters with relevance to photosystem II.

1 reference

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28 July 2018

Mechanism of oxidation reactions catalyzed by cytochrome p450 enzymes.

1 reference

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28 July 2018

Peroxide-utilizing biocatalysts: structural and functional diversity of heme-containing enzymes

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Dioxygen activation at mononuclear nonheme iron active sites: enzymes, models, and intermediates

1 reference

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28 July 2018

Structural, spectroscopic, and reactivity models for the manganese catalases.

1 reference

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28 July 2018

Quantum chemical studies of intermediates and reaction pathways in selected enzymes and catalytic synthetic systems

1 reference

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28 July 2018

Laser Flash Photolysis Formation and Direct Kinetic Studies of Manganese(V)-Oxo Porphyrin Intermediates

1 reference

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28 July 2018

The bioinorganic chemistry of iron in oxygenases and supramolecular assemblies

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28 July 2018

Desaturation and hydroxylation. Residues 148 and 324 of Arabidopsis FAD2, in addition to substrate chain length, exert a major influence in partitioning of catalytic specificity

1 reference

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28 July 2018

Multicopper Oxidases and Oxygenases

1 reference

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28 July 2018

Density-functional approximation for the correlation energy of the inhomogeneous electron gas

1 reference

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28 July 2018

Density-functional exchange-energy approximation with correct asymptotic behavior

1 reference

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28 July 2018

Oxygen activating nonheme iron enzymes.

1 reference

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28 July 2018

Cytochrome P-450 catalysis: radical intermediates and dehydrogenation reactions

1 reference

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28 July 2018

A unified mechanistic view of oxidative reactions catalysed by P-450 and related Fe-containing enzymes

1 reference

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28 July 2018

Mechanistic insights into hydride-transfer and electron-transfer reactions by a manganese(IV)-oxo porphyrin complex

1 reference

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29 October 2018

Hydrogen-atom abstraction reactions by manganese(V)- and manganese(IV)-oxo porphyrin complexes in aqueous solution

1 reference

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29 October 2018

Desaturases: emerging models for understanding functional diversification of diiron-containing enzymes

1 reference

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29 October 2018

Mössbauer and DFT study of the ferromagnetically coupled diiron(IV) precursor to a complex with an Fe(IV)(2)O(2) diamond core

1 reference

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29 October 2018

C-H oxidation by hydroxo manganese(v) porphyrins: a DFT study

1 reference

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29 October 2018

Manganese catalysts with molecular recognition functionality for selective alkene epoxidation

1 reference

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29 October 2018

The rebound mechanism in catalytic C-H oxidation by MnO(tpp)Cl from DFT studies: electronic nature of the active species

1 reference

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29 October 2018

Oxygen evolution catalysis by a dimanganese complex and its relation to photosynthetic water oxidation

1 reference

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29 October 2018

Electronic structure and reactivity of isomeric oxo-Mn(V) porphyrins: effects of spin-state crossing and pKa modulation.

1 reference

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Chromium- and manganese-salen promoted epoxidation of alkenes.

1 reference

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29 October 2018

Laser flash photolysis generation and kinetic studies of porphyrin-manganese-oxo intermediates. Rate constants for oxidations effected by porphyrin-Mn(V)-oxo species and apparent disproportionation equilibrium constants for porphyrin-Mn(IV)-oxo spec

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Fatty acid desaturases: selecting the dehydrogenation channel

1 reference

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Quantum mechanical/molecular mechanical investigation of the mechanism of C-H hydroxylation of camphor by cytochrome P450cam: theory supports a two-state rebound mechanism

1 reference

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Fatty acid desaturation: variations on an oxidative theme

1 reference

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29 October 2018

Isolation of an oxomanganese(V) porphyrin intermediate in the reaction of a manganese(III) porphyrin complex and H2O2 in aqueous solution

1 reference

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Dynamics of alkane hydroxylation at the non-heme diiron center in methane monooxygenase

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Desaturation reactions catalyzed by soluble methane monooxygenase

1 reference

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Investigations of the roles of the distal heme environment and the proximal heme iron ligand in peroxide activation by heme enzymes via molecular engineering of myoglobin

1 reference

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Characterization of the O(2)-evolving reaction catalyzed by [(terpy)(H2O)Mn(III)(O)2Mn(IV)(OH2)(terpy)](NO3)3 (terpy = 2,2':6,2"-terpyridine).

1 reference

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29 October 2018

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Two-state reactivity in alkane hydroxylation by non-heme iron-oxo complexes

1 reference

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12 December 2020

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1 reference

https://pubmed.ncbi.nlm.nih.gov/20481432

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inferred from PubMed ID database lookup

Oxygen economy of cytochrome P450: what is the origin of the mixed functionality as a dehydrogenase-oxidase enzyme compared with its normal function?

1 reference

https://pubmed.ncbi.nlm.nih.gov/20481432

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Epoxidation Catalysis by a Manganese Corrole and Isolation of an Oxomanganese(V) Corrole We acknowledge the partial support of this research by "The Fund for the Promotion of Research at the Technion"

1 reference

https://pubmed.ncbi.nlm.nih.gov/20481432

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inferred from PubMed ID database lookup

A functional model for O-O bond formation by the O2-evolving complex in photosystem II

1 reference

https://pubmed.ncbi.nlm.nih.gov/20481432

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Correlating structure with function in bacterial multicomponent monooxygenases and related diiron proteins

1 reference

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12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Molecular recognition in the selective oxygenation of saturated C-H bonds by a dimanganese catalyst

1 reference

https://pubmed.ncbi.nlm.nih.gov/20481432

12 December 2020

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Cytochrome P-450--catalyzed formation of delta 4-VPA, a toxic metabolite of valproic acid

1 reference

https://pubmed.ncbi.nlm.nih.gov/20481432

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Advances in homogeneous and heterogeneous catalytic asymmetric epoxidation

1 reference

https://pubmed.ncbi.nlm.nih.gov/20481432

12 December 2020

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Olefin epoxidation with inorganic peroxides. Solutions to four long-standing controversies on the mechanism of oxygen transfer

1 reference

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Transition-metal systems in biochemistry studied by high-accuracy quantum chemical methods

1 reference

https://pubmed.ncbi.nlm.nih.gov/20481432

12 December 2020

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Reactions of the diiron enzyme stearoyl-acyl carrier protein desaturase

1 reference

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The role of substrate in unmasking oxyl character in oxomanganese complexes: the key to selectivity?

1 reference

https://pubmed.ncbi.nlm.nih.gov/20481432

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An Fe2IVO2 Diamond Core Structure for the Key Intermediate Q of Methane Monooxygenase

1 reference

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Erratum: Density-functional approximation for the correlation energy of the inhomogeneous electron gas

1 reference

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Efficient heterogeneous oxidation of alkylarenes with molecular oxygen

1 reference

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From simple to supramolecular cytochrome P450 mimics

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4 June 2024

https://opencitations.net/index/api/v1/citations/10.1039/A804252G

Identifiers

10.1021/JA908744W

1 reference

Europe PubMed Central

PubMed publication ID

30 July 2017

PMC publication ID

1 reference

Europe PubMed Central

PubMed publication ID

30 July 2017

PubMed publication ID

1 reference

Europe PubMed Central

PubMed publication ID

30 July 2017

ResearchGate publication ID

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