(Q34698692)

English

Substituent effects on electrophilic catalysis by the carbonyl group: anatomy of the rate acceleration for PLP-catalyzed deprotonation of glycine.

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scholarly article

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22 January 2020

Substituent effects on electrophilic catalysis by the carbonyl group: anatomy of the rate acceleration for PLP-catalyzed deprotonation of glycine (English)

1 reference

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22 January 2020

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22 January 2020

2

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22 January 2020

John P. Richard

4

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22 January 2020

author name string

Enrique Riveiros

3

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22 January 2020

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16 February 2011

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22 January 2020

Journal of the American Chemical Society

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22 January 2020

133

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22 January 2020

9

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22 January 2020

3173-3183

1 reference

Europe PubMed Central

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22 January 2020

Internal proton transfer in the external pyridoxal 5'-phosphate Schiff base in dopa decarboxylase

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3060797

7 July 2018

Substituent effects on the thermodynamic stability of imines formed from glycine and aromatic aldehydes: implications for the catalytic activity of pyridoxal-5'-phosphate.

1 reference

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7 July 2018

Pyridoxal 5'-phosphate: electrophilic catalyst extraordinaire

1 reference

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7 July 2018

Tryptophan synthase: the workings of a channeling nanomachine

1 reference

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7 July 2018

Phosphate binding energy and catalysis by small and large molecules

1 reference

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7 July 2018

Glycine enolates: the effect of formation of iminium ions to simple ketones on alpha-amino carbon acidity and a comparison with pyridoxal iminium ions

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3060797

7 July 2018

Covalent catalysis by pyridoxal: evaluation of the effect of the cofactor on the carbon acidity of glycine

1 reference

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7 July 2018

A combined quantum mechanical and molecular mechanical study of the reaction mechanism and alpha-amino acidity in alanine racemase

1 reference

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7 July 2018

Role of Q52 in catalysis of decarboxylation and transamination in dialkylglycine decarboxylase.

1 reference

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7 July 2018

Serine hydroxymethyltransferase revisited

1 reference

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7 July 2018

Reaction specificity in pyridoxal phosphate enzymes

1 reference

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7 July 2018

On the importance of being zwitterionic: enzymatic catalysis of decarboxylation and deprotonation of cationic carbon

1 reference

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7 July 2018

Pyridoxal phosphate enzymes: mechanistic, structural, and evolutionary considerations

1 reference

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7 July 2018

A comparison of the electrophilic reactivities of Zn2+ and acetic acid as catalysts of enolization: imperatives for enzymatic catalysis of proton transfer at carbon

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3060797

7 July 2018

Threonine aldolase and alanine racemase: novel examples of convergent evolution in the superfamily of vitamin B6-dependent enzymes

1 reference

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7 July 2018

Strain and catalysis in aspartate aminotransferase

1 reference

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7 July 2018

Formation and stability of peptide enolates in aqueous solution.

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3060797

7 July 2018

From cofactor to enzymes. The molecular evolution of pyridoxal-5'-phosphate-dependent enzymes

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3060797

7 July 2018

Tryptophan synthase: a multienzyme complex with an intramolecular tunnel

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3060797

7 July 2018

Reaction mechanism of alanine racemase from Bacillus stearothermophilus: x-ray crystallographic studies of the enzyme bound with N-(5'-phosphopyridoxyl)alanine

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3060797

7 July 2018

Rapid kinetic and isotopic studies on dialkylglycine decarboxylase

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3060797

7 July 2018

Altering the reaction specificity of eukaryotic ornithine decarboxylase

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3060797

7 July 2018

Effects of the E177K mutation in D-amino acid transaminase. Studies on an essential coenzyme anchoring group that contributes to stereochemical fidelity

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3060797

7 July 2018

Structure, evolution and action of vitamin B6-dependent enzymes

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3060797

7 July 2018

Determination of the structure of alanine racemase from Bacillus stearothermophilus at 1.9-A resolution

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3060797

7 July 2018

Pyridoxal phosphate-dependent enzymes

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3060797

7 July 2018

Crystal structure of a D-amino acid aminotransferase: how the protein controls stereoselectivity

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3060797

7 July 2018

Mechanism of action of aspartate aminotransferase proposed on the basis of its spatial structure

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3060797

7 July 2018

Simplifying pyridoxal: practical methods for amino acid dynamic kinetic resolution

1 reference

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26 October 2018

Crystal structures of Aedes aegypti alanine glyoxylate aminotransferase

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3060797

26 October 2018

Carbon acidity of the alpha-pyridinium carbon of a pyridoxamine analog.

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3060797

26 October 2018

Kinetic and crystallographic analysis of active site mutants of Escherichia coli gamma-aminobutyrate aminotransferase

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3060797

26 October 2018

Ornithine decarboxylase promotes catalysis by binding the carboxylate in a buried pocket containing phenylalanine 397.

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3060797

26 October 2018

Formation and stability of enolates of acetamide and acetate anion: an Eigen plot for proton transfer at alpha-carbonyl carbon

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3060797

26 October 2018

Functional attributes of the phosphate group binding cup of pyridoxal phosphate-dependent enzymes

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3060797

26 October 2018

Keto-enol/enolate equilibria in the N-acetylamino-p-methylacetophenone system. Effect of a beta-nitrogen substituent.

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3060797

26 October 2018

Glycine enolates: the large effect of iminium ion formation on alpha-amino carbon acidity

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3060797

26 October 2018

pH studies on the mechanism of the pyridoxal phosphate-dependent dialkylglycine decarboxylase

1 reference

https://pubmed.ncbi.nlm.nih.gov/21323335

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Transient-state kinetics of the reaction of aspartate aminotransferase with aspartate at low pH reveals dual routes in the enzyme-substrate association process

1 reference

https://pubmed.ncbi.nlm.nih.gov/21323335

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Evidence for a two-base mechanism involving tyrosine-265 from arginine-219 mutants of alanine racemase

1 reference

https://pubmed.ncbi.nlm.nih.gov/21323335

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Identifiers

10.1021/JA110795M

1 reference

Europe PubMed Central

https://www.ebi.ac.uk/europepmc/webservices/rest/search?query=EXT_ID:21323335%20AND%20SRC:MED&resulttype=core&format=json

22 January 2020

1 reference

Europe PubMed Central

https://www.ebi.ac.uk/europepmc/webservices/rest/search?query=EXT_ID:21323335%20AND%20SRC:MED&resulttype=core&format=json

22 January 2020

1 reference

Europe PubMed Central

https://www.ebi.ac.uk/europepmc/webservices/rest/search?query=EXT_ID:21323335%20AND%20SRC:MED&resulttype=core&format=json

22 January 2020

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