(Q37406215)

English

Catalytic Reductive ortho-C-H Silylation of Phenols with Traceless, Versatile Acetal Directing Groups and Synthetic Applications of Dioxasilines

scientific article published on 06 June 2016

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12 March 2020

Catalytic Reductive ortho-C-H Silylation of Phenols with Traceless, Versatile Acetal Directing Groups and Synthetic Applications of Dioxasilines (English)

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12 March 2020

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12 March 2020

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Yuanda Hua

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12 March 2020

Parham Asgari

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12 March 2020

Thirupataiah Avullala

3

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16 June 2016

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12 March 2020

Journal of the American Chemical Society

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12 March 2020

138

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12 March 2020

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12 March 2020

7982-7991

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12 March 2020

Silylation of C–H bonds in aromatic heterocycles by an Earth-abundant metal catalyst

1 reference

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6 September 2017

General method for the synthesis of salicylic acids from phenols through palladium-catalyzed silanol-directed C-H carboxylation

1 reference

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6 September 2017

Conversion of 1-alkenes into 1,4-diols through an auxiliary-mediated formal homoallylic C-H oxidation

1 reference

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6 September 2017

Organosilicon molecules with medicinal applications

1 reference

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The hexadehydro-Diels-Alder reaction

1 reference

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6 September 2017

Gold-catalyzed direct arylation

1 reference

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6 September 2017

C-H bond functionalization: emerging synthetic tools for natural products and pharmaceuticals

1 reference

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6 September 2017

Pd-catalyzed modifiable silanol-directed aromatic C-H oxygenation

1 reference

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6 September 2017

A comprehensive history of arynes in natural product total synthesis

1 reference

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6 September 2017

Arynes and cyclohexyne in natural product synthesis

1 reference

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6 September 2017

General and practical one-pot synthesis of dihydrobenzosiloles from styrenes

1 reference

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6 September 2017

Synthesis of catechols from phenols via Pd-catalyzed silanol-directed C-H oxygenation

1 reference

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6 September 2017

Silanol: a traceless directing group for Pd-catalyzed o-alkenylation of phenols

1 reference

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6 September 2017

Silicon-based cross-coupling reaction: an environmentally benign version

1 reference

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6 September 2017

Chiral Brønsted acids for asymmetric organocatalysis

1 reference

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6 September 2017

Recent developments in natural product synthesis using metal-catalysed C-H bond functionalisation

1 reference

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6 September 2017

Removable directing groups in organic synthesis and catalysis

1 reference

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6 September 2017

C-H functionalization logic in total synthesis

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=5103641

6 September 2017

Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=5103641

6 September 2017

Transition-metal-catalyzed direct arylation of (hetero)arenes by C-H bond cleavage.

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=5103641

6 September 2017

Recent advances in aryl-aryl bond formation by direct arylation.

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=5103641

6 September 2017

Palladium(II)-catalyzed C-H activation/C-C cross-coupling reactions: versatility and practicality

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=5103641

6 September 2017

Rhodium-catalyzed C-C bond formation via heteroatom-directed C-H bond activation

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=5103641

6 September 2017

Cross-coupling reactions of aromatic and heteroaromatic silanolates with aromatic and heteroaromatic halides

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=5103641

6 September 2017

Palladium-catalyzed cross-coupling reactions of organosilanols and their salts: practical alternatives to boron- and tin-based methods

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=5103641

6 September 2017

Catalytic C–H functionalization by metal carbenoid and nitrenoid insertion

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=5103641

6 September 2017

Direct transition metal-catalyzed functionalization of heteroaromatic compounds

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=5103641

6 September 2017

Aryl-aryl bond formation by transition-metal-catalyzed direct arylation.

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=5103641

6 September 2017

Palladium-catalyzed benzene arylation: incorporation of catalytic pivalic acid as a proton shuttle and a key element in catalyst design

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=5103641

6 September 2017

BINOL: a versatile chiral reagent

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=5103641

6 September 2017

Recent Developments in the Synthesis and Structure of Organosilanols†

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=5103641

6 September 2017

Beyond thermodynamic acidity: a perspective on the complex-induced proximity effect (CIPE) in deprotonation reactions

1 reference

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6 September 2017

3,4-Dihydroxyphenylalanine and 5-hydroxytryptophan as reserpine antagonists

1 reference

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6 September 2017

The combinatorial synthesis of bicyclic privileged structures or privileged substructures.

1 reference

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6 September 2017

One century of aryne chemistry

1 reference

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6 September 2017

Hetero- and Metallasiloxanes Derived from Silanediols, Disilanols, Silanetriols, and Trisilanols

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=5103641

6 September 2017

Viracept (nelfinavir mesylate, AG1343): a potent, orally bioavailable inhibitor of HIV-1 protease

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=5103641

6 September 2017

Biologically active compounds containing 2,3-duhydroxybenzoic acid and serine formed by Escherichia coli

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=5103641

6 September 2017

Palladium- and copper-catalyzed arylation of carbon-hydrogen bonds

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=5103641

14 September 2017

Iridium-catalyzed arene ortho-silylation by formal hydroxyl-directed C-H activation

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=5103641

26 June 2018

Highly efficient diastereoselective reduction of alpha-fluoroimines

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=5103641

26 June 2018

Catalytic Silylation of Unactivated C-H Bonds

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=5103641

2 September 2018

Reductive arene ortho-silanolization of aromatic esters with hydridosilyl acetals.

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=5103641

2 September 2018

Mechanism of the rhodium-catalyzed silylation of arene C-H bonds

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=5103641

2 September 2018

Iridium-catalyzed regioselective silylation of aromatic and benzylic C-H bonds directed by a secondary amine

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=5103641

2 September 2018

Rhodium-catalyzed intermolecular C-H silylation of arenes with high steric regiocontrol

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=5103641

2 September 2018

Gold-catalyzed oxidative coupling of arylsilanes and arenes: origin of selectivity and improved precatalyst

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=5103641

2 September 2018

Carboxylate-assisted ruthenium-catalyzed alkyne annulations by C-H/Het-H bond functionalizations

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=5103641

2 September 2018

Sequential protocol for C(sp3)-H carboxylation with CO2: transition-metal-catalyzed benzylic C-H silylation and fluoride-mediated carboxylation.

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=5103641

2 September 2018

Controlling site selectivity in palladium-catalyzed C-H bond functionalization

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=5103641

2 September 2018

On the interpretation of deuterium kinetic isotope effects in C-H bond functionalizations by transition-metal complexes

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=5103641

2 September 2018

Development and mechanistic investigation of a highly efficient iridium(V) silyl complex for the reduction of tertiary amides to amines.

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=5103641

2 September 2018

Divergent C-H functionalizations directed by sulfonamide pharmacophores: late-stage diversification as a tool for drug discovery

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=5103641

2 September 2018

Rhodium-catalyzed synthesis of silafluorene derivatives via cleavage of silicon-hydrogen and carbon-hydrogen bonds

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=5103641

2 September 2018

Application of the sila-Friedel-Crafts reaction to the synthesis of π-extended silole derivatives and their properties

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=5103641

2 September 2018

A meta-selective copper-catalyzed C-H bond arylation

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=5103641

2 September 2018

Modular approach to silicon-bridged biaryls: palladium-catalyzed intramolecular coupling of 2-(arylsilyl)aryl triflates

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=5103641

2 September 2018

Iron-mediated direct arylation of unactivated arenes.

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=5103641

2 September 2018

Rhodium-catalyzed silylation of aromatic carbon-hydrogen bonds in 2-arylpyridines with disilane

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=5103641

2 September 2018

Palladium-catalyzed direct arylation of (hetero)arenes with aryl boronic acids

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=5103641

2 September 2018

Stereocontrolled synthesis of methyl silanediol peptide mimics

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=5103641

2 September 2018

Chelation-controlled diastereoselective reduction of alpha-fluoroketones

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=5103641

2 September 2018

Application of directed orthometalation toward the synthesis of aryl siloxanes

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=5103641

2 September 2018

Why are silyl ethers conformationally different from alkyl ethers? Chair-chair conformational equilibria in silyloxycyclohexanes and their dependence on the substituents on silicon. The wider roles of eclipsing, of 1,3-repulsive steric interactions,

1 reference

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2 September 2018

Direct Synthesis of Aryl Halosilanes through Iridium(I)‐Catalyzed Aromatic CH Silylation by Disilanes

1 reference

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2 September 2018

Silicon-based metalloprotease inhibitors: synthesis and evaluation of silanol and silanediol peptide analogues as inhibitors of angiotensin-converting enzyme

1 reference

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2 September 2018

Carboxylic Acids as Traceless Directing Groups for Formal meta-Selective Direct Arylation

1 reference

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3 December 2018

Organosilanols as Catalysts in Asymmetric Aryl Transfer Reactions

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=5103641

3 December 2018

C-H bond functionalization in complex organic synthesis

1 reference

https://pubmed.ncbi.nlm.nih.gov/27265033

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Scandium-catalyzed silylation of aromatic C-H bonds

1 reference

https://pubmed.ncbi.nlm.nih.gov/27265033

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Rhodium(III)-Catalyzed CH Activation of Arenes Using a Versatile and Removable Triazene Directing Group

1 reference

https://pubmed.ncbi.nlm.nih.gov/27265033

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Efficient reduction of esters to aldehydes through iridium-catalyzed hydrosilylation

1 reference

https://pubmed.ncbi.nlm.nih.gov/27265033

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Modular Approach to Reductive C(sp2)-H and C(sp3)-H Silylation of Carboxylic Acid Derivatives through Single-Pot, Sequential Transition Metal Catalysis

1 reference

https://pubmed.ncbi.nlm.nih.gov/27265033

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Silanol as a removable directing group for the Pd(II)-catalyzed direct olefination of arenes

1 reference

https://pubmed.ncbi.nlm.nih.gov/27265033

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

1,5-Migration of rhodium via C-H bond activation in catalytic decyanative silylation of nitriles

1 reference

https://pubmed.ncbi.nlm.nih.gov/27265033

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Rhodium-catalyzed intramolecular silylation of unactivated C(sp3)-H bonds

1 reference

https://pubmed.ncbi.nlm.nih.gov/27265033

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

A Highly Para-Selective Copper(II)-Catalyzed Direct Arylation of Aniline and Phenol Derivatives

1 reference

https://pubmed.ncbi.nlm.nih.gov/27265033

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Cooperative Catalytic Activation of Si−H Bonds by a Polar Ru−S Bond: Regioselective Low-Temperature C−H Silylation of Indoles under Neutral Conditions by a Friedel−Crafts Mechanism

1 reference

https://pubmed.ncbi.nlm.nih.gov/27265033

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Pd-catalyzed oxidative coupling with organometallic reagents via C-H activation

1 reference

https://pubmed.ncbi.nlm.nih.gov/27265033

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Palladium(II)-catalyzed direct alkenylation and arylation of arenes: removable 2-pyridylsulfinyl group assisted C-H bond activation

1 reference

https://pubmed.ncbi.nlm.nih.gov/27265033

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Silanediols: a new class of hydrogen bond donor catalysts

1 reference

https://pubmed.ncbi.nlm.nih.gov/27265033

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Nickel-catalyzed direct C-H arylation and alkenylation of heteroarenes with organosilicon reagents

1 reference

https://pubmed.ncbi.nlm.nih.gov/27265033

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Chelation-controlled addition of organozincs to α-chloro aldimines

1 reference

https://pubmed.ncbi.nlm.nih.gov/27265033

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Iridium-catalyzed silylation of aryl C-H bonds

1 reference

https://pubmed.ncbi.nlm.nih.gov/27265033

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Pd(II)-catalysed C-H functionalisation of indoles and pyrroles assisted by the removable N-(2-pyridyl)sulfonyl group: C2-alkenylation and dehydrogenative homocoupling

1 reference

https://pubmed.ncbi.nlm.nih.gov/27265033

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Enabling the use of heterocyclic arynes in chemical synthesis

1 reference

https://pubmed.ncbi.nlm.nih.gov/27265033

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Palladium-catalyzed Hiyama cross-couplings of aryl arenesulfonates with arylsilanes

1 reference

https://pubmed.ncbi.nlm.nih.gov/27265033

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Cooperative hydrogen-bonding effects in silanediol catalysis

1 reference

https://pubmed.ncbi.nlm.nih.gov/27265033

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Hybrid gold/chiral Brønsted acid relay catalysis allows an enantioselective synthesis of (-)-5-epi-eupomatilone-6

1 reference

https://pubmed.ncbi.nlm.nih.gov/27265033

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Iridium-catalyzed reduction of secondary amides to secondary amines and imines by diethylsilane

1 reference

https://pubmed.ncbi.nlm.nih.gov/27265033

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Palladium-catalyzed silylation of aryl bromides leading to functionalized aryldimethylsilanols

1 reference

https://pubmed.ncbi.nlm.nih.gov/27265033

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Studies on the mechanism of B(C(6)F(5))(3)-catalyzed hydrosilation of carbonyl functions

1 reference

https://pubmed.ncbi.nlm.nih.gov/27265033

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Identifiers

10.1021/JACS.6B04018

1 reference

Europe PubMed Central

PMC publication ID

https://www.ebi.ac.uk/europepmc/webservices/rest/search?query=EXT_ID:27265033%20AND%20SRC:MED&resulttype=core&format=json

12 March 2020

PMC publication ID

1 reference

Europe PubMed Central

PMC publication ID

https://www.ebi.ac.uk/europepmc/webservices/rest/search?query=EXT_ID:27265033%20AND%20SRC:MED&resulttype=core&format=json

12 March 2020

PubMed publication ID

1 reference

Europe PubMed Central

PMC publication ID

https://www.ebi.ac.uk/europepmc/webservices/rest/search?query=EXT_ID:27265033%20AND%20SRC:MED&resulttype=core&format=json

12 March 2020

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