(Q38002268)

26 August 2017

High-valent organometallic copper and palladium in catalysis (English)

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26 August 2017

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Melanie S Sanford

2

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author name string

Amanda J Hickman

series ordinal

1

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PMC publication ID

4384170

26 August 2017

language of work or name

English

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publication date

11 April 2012

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26 August 2017

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26 August 2017

484

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26 August 2017

7393

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26 August 2017

177-185

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https://scigraph.springernature.com/pub.10.1038/nature11008

26 August 2017

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cites work

C-H bond activation at palladium(IV) centers

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Synthesis, isolation, and characterization of an organometallic triiodopalladium(IV) complex. Quantitative and regioselective synthesis of two C-I reductive elimination products

6 September 2017

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Mechanistic and computational studies of oxidatively-induced aryl-CF3 bond-formation at Pd: rational design of room temperature aryl trifluoromethylation

6 September 2017

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Large-scale applications of transition metal-catalyzed couplings for the synthesis of pharmaceuticals

6 September 2017

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https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4384170

The mechanism of the modified Ullmann reaction

6 September 2017

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https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4384170

On the mechanism of palladium-catalyzed aromatic C-H oxidation

6 September 2017

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Computational explorations of mechanisms and ligand-directed selectivities of copper-catalyzed Ullmann-type reactions

6 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4384170

Organopalladium(IV) chemistry

6 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4384170

Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions

6 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4384170

The organometallic fluorine chemistry of palladium and rhodium: studies toward aromatic fluorination

6 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4384170

Copper-mediated coupling reactions and their applications in natural products and designed biomolecules synthesis

6 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4384170

Fluorine in pharmaceuticals: looking beyond intuition

6 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4384170

Organocuprate conjugate addition: the square-planar "CuIII" intermediate

6 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4384170

Rapid injection NMR in mechanistic organocopper chemistry. Preparation of the elusive copper(III) intermediate

6 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4384170

Electronic effects on reductive elimination to form carbon-carbon and carbon-heteroatom bonds from palladium(II) complexes

6 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4384170

Selected patented cross-coupling reaction technologies

6 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4384170

Wherefore Art Thou Copper? Structures and Reaction Mechanisms of Organocuprate Clusters in Organic Chemistry

6 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4384170

Acetylenic Coupling: A Powerful Tool in Molecular Construction

6 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4384170

Mechanism of C-F reductive elimination from palladium(IV) fluorides

6 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4384170

The palladium-catalyzed trifluoromethylation of aryl chlorides

14 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4384170

Alternative mechanistic explanation for ligand-dependent selectivities in copper-catalyzed N- and O-arylation reactions.

28 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4384170

Oxidation of a cyclometalated Pd(II) dimer with "CF3+": formation and reactivity of a catalytically competent monomeric Pd(IV) aquo complex

23 June 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4384170

Silver-catalyzed late-stage fluorination

23 June 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4384170

Palladium-catalyzed oxidative arylhalogenation of alkenes: synthetic scope and mechanistic insights

23 June 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4384170

Synthetic and mechanistic studies of Pd-catalyzed C-H arylation with diaryliodonium salts: evidence for a bimetallic high oxidation state Pd intermediate

23 June 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4384170

Synthesis and reactivity of a mono-sigma-aryl palladium(IV) fluoride complex

23 June 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4384170

Copper complexes of anionic nitrogen ligands in the amidation and imidation of aryl halides

23 June 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4384170

Copper-catalyzed aerobic oxidative functionalization of an arene C-H bond: evidence for an aryl-copper(III) intermediate

23 June 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4384170

Copper(II)-catalyzed ortho-acyloxylation of the 2-arylpyridines sp(2) C-H bonds with anhydrides, using O(2) as terminal oxidant

31 August 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4384170

Pd(II)-catalyzed ortho-trifluoromethylation of arenes using TFA as a promoter

31 August 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4384170

Bimetallic palladium catalysis: direct observation of Pd(III)-Pd(III) intermediates

31 August 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4384170

Chelating N-Heterocyclic Carbene Alkoxide as a Supporting Ligand for PdII/IVC−H Bond Functionalization Catalysis

31 August 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4384170

Palladium-catalyzed carboamination of alkenes promoted by N-fluorobenzenesulfonimide via C-H activation of arenes.

31 August 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4384170

Cu(II)-mediated oxidative intermolecular ortho C-H functionalisation using tetrahydropyrimidine as the directing group.

31 August 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4384170

Copper-catalyzed synthesis of benzoxazoles via a regioselective C-H functionalization/C-O bond formation under an air atmosphere

31 August 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4384170

A meta-selective copper-catalyzed C-H bond arylation

31 August 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4384170

Preparation of sigma- and pi-allylcopper(III) intermediates in SN2 and SN2' reactions of organocuprate(I) reagents with allylic substrates

31 August 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4384170

Catalytic aerobic oxidation of substituted 8-methylquinolines in Pd(II)-2,6-pyridinedicarboxylic acid systems

31 August 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4384170

Synthesis of 2-arylbenzoxazoles by copper-catalyzed intramolecular oxidative C-O coupling of benzanilides

31 August 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4384170

Cu(II)-catalyzed direct and site-selective arylation of indoles under mild conditions

31 August 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4384170

Reactivity of Pd(II) complexes with electrophilic chlorinating reagents: isolation of Pd(IV) products and observation of C-Cl bond-forming reductive elimination

31 August 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4384170

A highly selective catalytic method for the oxidative functionalization of C-H bonds

31 August 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4384170

Directly Observed Reductive Elimination of Aryl Halides from Monomeric Arylpalladium(II) Halide Complexes

31 August 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4384170

Interactions of aziridines with nickel complexes: oxidative-addition and reductive-elimination reactions that break and make C-N bonds

31 August 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4384170

Experimental evidence supporting a CuIII intermediate in cross-coupling reactions of allylic esters with diallylcuprate species

31 August 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4384170

Catalytic CC, CN, and CO Ullmann-Type Coupling Reactions

31 August 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=4384170

Copper in cross-coupling reactions

1 October 2018

1 reference

https://api.crossref.org/works/10.1038%2FNATURE11008

Recent Applications of Palladium-Catalyzed Coupling Reactions in the Pharmaceutical, Agrochemical, and Fine Chemical Industries

21 January 2018

1 reference

https://api.crossref.org/works/10.1038%2FNATURE11008

Aromatic haloethylation with palladium and copper halides

21 January 2018

1 reference

https://api.crossref.org/works/10.1038%2FNATURE11008

Palladium-Catalyzed Intramolecular Chloroamination of Alkenes

21 January 2018

1 reference

https://api.crossref.org/works/10.1038%2FNATURE11008

Room Temperature Palladium-Catalyzed 2-Arylation of Indoles

21 January 2018

1 reference

https://api.crossref.org/works/10.1038%2FNATURE11008

Highly Regioselective Catalytic Oxidative Coupling Reactions: Synthetic and Mechanistic Investigations

21 January 2018

1 reference

https://api.crossref.org/works/10.1038%2FNATURE11008

Catalyst Control of Site Selectivity in the PdII/IV-Catalyzed Direct Arylation of Naphthalene

21 January 2018

1 reference

https://api.crossref.org/works/10.1038%2FNATURE11008

Oxidatively Induced Carbon−Halogen Bond-Forming Reactions at Nickel

21 January 2018

1 reference

https://api.crossref.org/works/10.1038%2FNATURE11008

Direct observation of CuI/CuIII redox steps relevant to Ullmann-type coupling reactions

21 January 2018

1 reference

https://api.crossref.org/works/10.1038%2FNATURE11008

Nucleophilic Aryl Fluorination and Aryl Halide Exchange Mediated by a CuI/CuIIICatalytic Cycle

21 January 2018

1 reference

https://api.crossref.org/works/10.1038%2FNATURE11008

High-oxidation-state palladium catalysis: new reactivity for organic synthesis

21 January 2018

1 reference

12 December 2020

Emergence of palladium(IV) chemistry in synthesis and catalysis

1 reference

12 December 2020

Copper-catalyzed aerobic oxidative amidation of terminal alkynes: efficient synthesis of ynamides

1 reference

12 December 2020

Mechanistic understanding of the unexpected meta selectivity in copper-catalyzed anilide C-H bond arylation

1 reference

12 December 2020

Copper-catalyzed trifluoromethylation of aryl boronic acids using a CF3+ reagent

1 reference

12 December 2020

Carbon-nitrogen bond formation involving well-defined aryl-copper(III) complexes

1 reference

12 December 2020

C-H functionalization/C-N bond formation: copper-catalyzed synthesis of benzimidazoles from amidines

1 reference

12 December 2020

Aryl CbondH activation by CuII to form an organometallic aryl-CuIII species: a novel twist on copper disproportionation

1 reference

12 December 2020

Exploring the nickel-catalyzed oxidation of alkenes: a diamination by sulfamide transfer

1 reference

12 December 2020

Diamagnetic-paramagnetic conversion of tris(2-pyridylthio)methylcopper(III) through a structural change from trigonal bipyramidal to octahedral

1 reference

12 December 2020

NMR-Detection of Cu(III) Intermediates in Substitution Reactions of Alkyl Halides with Gilman Cuprates

1 reference

12 December 2020

Copper-catalyzed aerobic oxidative C-H functionalizations: trends and mechanistic insights

1 reference

12 December 2020

Neutral organocopper(III) complexes

1 reference

12 December 2020

Pd(II)-catalyzed hydroxylation of arenes with 1 atm of O(2) or air

1 reference

12 December 2020

Cu(II)-catalyzed functionalizations of aryl C-H bonds using O2 as an oxidant

1 reference

12 December 2020

Organocuprate cross-coupling: the central role of the copper(III) intermediate and the importance of the copper(I) precursor

1 reference

12 December 2020

Organopalladium and platinum chemistry in oxidising milieu as models for organic synthesis involving the higher oxidation states of palladium

1 reference

12 December 2020

Copper-catalyzed aerobic oxidative coupling of terminal alkynes with H-phosphonates leading to alkynylphosphonates

1 reference

12 December 2020

Palladium-catalyzed intramolecular aminofluorination of unactivated alkenes

1 reference

12 December 2020

High yield syntheses of stable, singly bonded Pd2(6+) compounds

1 reference

12 December 2020

The Bioinorganic and Organometallic Chemistry of Copper(III)

1 reference

https://api.crossref.org/works/10.1038%2FNATURE11008

7 January 2021

Aryl CbH Activation by CuII To Form an Organometallic Arylâ CuIII Species: A Novel Twist on Copper Disproportionation This research was supported by MICYT of Spain through project PBQ2000-0548 and with the grant SGR-3102-UG-01 as well as the Dist

1 reference

https://api.crossref.org/works/10.1038%2FNATURE11008

7 January 2021

The oxidative addition of lodomethane to [PdMe2(bpy)] and the X-ray structure of the organopalladium(IV) product fac-[PdMe3(bpy)l](bpy = 2,2′-bipyridyl)

1 reference

https://api.crossref.org/works/10.1038%2FNATURE11008

7 January 2021

The Mizoroki–Heck Reaction

1 reference

https://api.crossref.org/works/10.1038%2FNATURE11008

7 January 2021

Identifiers

DOI

10.1038/NATURE11008

1 reference

26 August 2017

1 reference

PMC publication ID

4384170

26 August 2017

PubMed publication ID

22498623

1 reference

PMC publication ID

4384170