(Q38310398)

2 September 2017

title

The reactivity of the active metal oxo and hydroxo intermediates and their implications in oxidations (English)

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2 September 2017

0 references

1

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https://www.ebi.ac.uk/europepmc/webservices/rest/search?query=EXT_ID:25566588%20AND%20SRC:MED&resulttype=core&format=json

13 June 2020

author name string

Guochuan Yin

series ordinal

2

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https://www.ebi.ac.uk/europepmc/webservices/rest/search?query=EXT_ID:25566588%20AND%20SRC:MED&resulttype=core&format=json

13 June 2020

publication date

1 March 2015

1 reference

2 September 2017

published in

Chemical Society Reviews

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https://www.ebi.ac.uk/europepmc/webservices/rest/search?query=EXT_ID:25566588%20AND%20SRC:MED&resulttype=core&format=json

13 June 2020

volume

44

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https://www.ebi.ac.uk/europepmc/webservices/rest/search?query=EXT_ID:25566588%20AND%20SRC:MED&resulttype=core&format=json

13 June 2020

issue

5

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https://www.ebi.ac.uk/europepmc/webservices/rest/search?query=EXT_ID:25566588%20AND%20SRC:MED&resulttype=core&format=json

13 June 2020

page(s)

1083-1100

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https://www.ebi.ac.uk/europepmc/webservices/rest/search?query=EXT_ID:25566588%20AND%20SRC:MED&resulttype=core&format=json

Thermochemistry of proton-coupled electron transfer reagents and its implications

13 June 2020

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Oxoiron(IV) in chloroperoxidase compound II is basic: implications for P450 chemistry

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Manganese catalysts for C-H activation: an experimental/theoretical study identifies the stereoelectronic factor that controls the switch between hydroxylation and desaturation pathways

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Hydroxylation by the hydroperoxy-iron species in cytochrome P450 enzymes

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Hydrocarbon oxidation by Bis-mu-oxo manganese dimers: electron transfer, hydride transfer, and hydrogen atom transfer mechanisms

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Mechanistic insights into hydride-transfer and electron-transfer reactions by a manganese(IV)-oxo porphyrin complex

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Ruthenium porphyrin-catalyzed aerobic oxidation of terminal aryl alkenes to aldehydes by a tandem epoxidation-isomerization pathway

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Caldariomyces fumago chloroperoxidase catalyzes the oxidative dehalogenation of chlorophenols by a mechanism involving two one-electron steps

21 January 2018

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Mechanistic investigations of the reaction of an iron(III) octa-anionic porphyrin complex with hydrogen peroxide and the catalyzed oxidation of diammonium-2,2'-azinobis(3-ethylbenzothiazoline-6-sulfonate).

21 January 2018

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Probing the Compound I-like reactivity of a bare high-valent oxo iron porphyrin complex: the oxidation of tertiary amines

21 January 2018

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C-H bond cleavage with reductants: re-investigating the reactivity of monomeric Mn(III/IV)-oxo complexes and the role of oxo ligand basicity

21 January 2018

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Direct kinetic studies of atom transfer and electron transfer reactions of hydroperoxo and high-valent oxo complexes of chromium

21 January 2018

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Electron transfer-oxygen transfer oxygenation of sulfides catalyzed by the H5PV2Mo10O40 polyoxometalate

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Manganese lipoxygenase. Discovery of a bis-allylic hydroperoxide as product and intermediate in a lipoxygenase reaction.

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Structural and spectroscopic features of a cis (hydroxo)-Fe(III)-(carboxylato) configuration as an active site model for lipoxygenases

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C-H activation by a mononuclear manganese(III) hydroxide complex: synthesis and characterization of a manganese-lipoxygenase mimic?

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Oxidative reactivity difference among the metal oxo and metal hydroxo moieties: pH dependent hydrogen abstraction by a manganese(IV) complex having two hydroxide ligands

21 January 2018

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Transient intermediates from Mn(salen) with sterically hindered mesityl groups: interconversion between MnIV-phenolate and MnIII-phenoxyl radicals as an origin for unique reactivity

21 January 2018

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Reactivities of Fe(IV) complexes with oxo, hydroxo, and alkylperoxo ligands: an experimental and computational study

21 January 2018

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Synthesis and structural characterization of a series of Mn(III)OR complexes, including a water-soluble Mn(III)OH that promotes aerobic hydrogen-atom transfer

21 January 2018

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21 January 2018

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21 January 2018

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21 January 2018

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Lewis-acid-promoted stoichiometric and catalytic oxidations by manganese complexes having cross-bridged cyclam ligand: a comprehensive study

21 January 2018

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21 January 2018

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Redox inactive metal ion promoted C-H activation of benzene to phenol with Pd(II)(bpym): demonstrating new strategies in catalyst designs.

21 January 2018

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Evidence for a Precursor Complex in CH Hydrogen Atom Transfer Reactions Mediated by a Manganese(IV) Oxo Complex

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21 January 2018

Identifiers

DOI

10.1039/C4CS00244J

1 reference

https://www.ebi.ac.uk/europepmc/webservices/rest/search?query=EXT_ID:25566588%20AND%20SRC:MED&resulttype=core&format=json

13 June 2020

1 reference