(Q40972618)

English

Closer insight into the reactivity of TMP-dialkyl zincates in directed ortho-zincation of anisole: experimental evidence of amido basicity and structural elucidation of key reaction intermediates

scientific article published on February 2009

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scholarly article

1 reference

Europe PubMed Central

PMC publication ID

25 September 2017

Closer insight into the reactivity of TMP-dialkyl zincates in directed ortho-zincation of anisole: experimental evidence of amido basicity and structural elucidation of key reaction intermediates (English)

1 reference

Europe PubMed Central

PMC publication ID

25 September 2017

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Eva Hevia

3

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Robert E. Mulvey

object named as

Robert E Mulvey

6

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object named as

William Clegg

1

0 references

author name string

Ben Conway

2

1 reference

Europe PubMed Central

PMC publication ID

25 September 2017

Matthew D McCall

4

1 reference

Europe PubMed Central

PMC publication ID

25 September 2017

Luca Russo

5

1 reference

Europe PubMed Central

PMC publication ID

25 September 2017

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publication date

1 February 2009

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Europe PubMed Central

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25 September 2017

Journal of the American Chemical Society

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Europe PubMed Central

PMC publication ID

25 September 2017

131

1 reference

Europe PubMed Central

PMC publication ID

25 September 2017

6

1 reference

Europe PubMed Central

PMC publication ID

25 September 2017

2375-2384

1 reference

Europe PubMed Central

PMC publication ID

25 September 2017

A short history of SHELX

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3662405

25 September 2017

Deprotonative metalation using ate compounds: synergy, synthesis, and structure building

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3662405

25 September 2017

Development of highly chemoselective bulky zincate complex, tBu4ZnLi2: design, structure, and practical applications in small-/macromolecular synthesis

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3662405

19 August 2018

A new interpretation of the reaction pathway of deprotonative metalation with TMP-Zn-ate/TMEDA Complex [TMEDA.Na(micro-tBu)(micro-TMP)Zn(tBu)].

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3662405

19 August 2018

Generation and suppression of 3-/4-functionalized benzynes using zinc ate base (TMP-Zn-ate): new approaches to multisubstituted benzenes.

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3662405

19 August 2018

Isolation and structural elucidation of a key aluminoaromatic intermediate and evidence for dismutation phenomena in TMP-alumination chemistry.

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3662405

19 August 2018

Sodium dialkyl-amidozincates: alkyl or amido bases? An experimental and theoretical case study

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3662405

19 August 2018

Generation of functionalized asymmetric benzynes with TMP-zincates. Effects of ligands on selectivity and reactivity of zincates

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3662405

19 August 2018

Structure and Reaction Pathway of TMP-Zincate: Amido Base or Alkyl Base?

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3662405

2 December 2018

Toward a Protecting-Group-Free Halogen−Metal Exchange Reaction: Practical, Chemoselective Metalation of Functionalized Aromatic Halides Using Dianion-type Zincate,tBu4ZnLi2

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3662405

2 December 2018

Alkali-Metal-Mediated Zincation of Anisole: Synthesis and Structures of Three Instructive Ortho-Zincated Complexes

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3662405

2 December 2018

Post-Metalation Structural Insights into the Use of Alkali-Metal-Mediated Zincation for Directedortho-Metalation of a Tertiary Aromatic Amide

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3662405

2 December 2018

Pre-Metalation Structural Insights into the Use of Alkali-Metal-Mediated Zincation for Directedortho-Metalation of a Tertiary Aromatic Amide

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3662405

2 December 2018

Alkali-Metal-Mediated Zincation of Ferrocene: Synthesis, Structure, and Reactivity of a Lithium Tmp/Zincate Reagent

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3662405

2 December 2018

On the Mechanism of the Ortho-Directed Metalation of Anisole by n-Butyllithium

1 reference

https://pubmed.ncbi.nlm.nih.gov/19199628

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

The direct alpha-zincation of amides, phosphonates and phosphine oxides by H-Zn exchange

1 reference

https://pubmed.ncbi.nlm.nih.gov/19199628

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Origin of chemoselectivity of TMP zincate bases and differences between TMP zincate and alkyl lithium reagents: a DFT study on model systems

1 reference

https://pubmed.ncbi.nlm.nih.gov/19199628

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Ligand-activated lithium-mediated zincation of N-phenylpyrrole

1 reference

https://pubmed.ncbi.nlm.nih.gov/19199628

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

NMR Spectroscopic Structural Determination of Organozinc Reagents: Evidence for "Highly Coordinated" Zincates

1 reference

https://pubmed.ncbi.nlm.nih.gov/19199628

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Identifiers

10.1021/JA8087168

1 reference

Europe PubMed Central

PMC publication ID

25 September 2017

PMC publication ID

1 reference

Europe PubMed Central

PMC publication ID

25 September 2017

PubMed publication ID

1 reference

Europe PubMed Central

PMC publication ID

25 September 2017

ResearchGate publication ID

0 references

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