(Q44295414)

English

carbonolide B

chemical compound

(+)-carbonolide B(I)
[(4R,5R,6S,7R,9R,11Z,13Z,16R)-6-hydroxy-5-methoxy-9,16-dimethyl-2,10-dioxo-7-(2-oxoethyl)-1-oxacyclohexadeca-11,13-dien-4-yl] acetate
C22H32O8

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type of chemical entity

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subclass of

chemical compound

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chemical structure

Carbonolide B.png
300 × 300; 4 KB

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mass

424.2097179839999 dalton

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chemical formula

C₂₂H₃₂O₈

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canonical SMILES

CC1CC=CC=CC(=O)C(CC(C(C(C(CC(=O)O1)OC(=O)C)OC)O)CC=O)C

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isomeric SMILES

C[C@@H]1C/C=C\C=C/C(=O)[C@@H](C[C@@H]([C@@H]([C@H]([C@@H](CC(=O)O1)OC(=O)C)OC)O)CC=O)C

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described by source

Chemical & Pharmaceutical Bulletin

title

STEREOSELECTIVE TOTAL SYNTHESIS OF 16-MEMBERED MACROLIDE AGLYCONS, LEUCONOLIDES AND MARIDONOLIDES - MACROCYCLIC STEREOCONTROL BASED ON CONFORMATIONAL-ANALYSIS OF THE 16-MEMBERED MACROLIDE RING (English)

publication date

November 1991

author name string

NAKAJIMA, N (NAKAJIMA, N); MATSUSHIMA, T (MATSUSHIMA, T); YONEMITSU, O (YONEMITSU, O); GOTO, H (GOTO, H); OSAWA, E (OSAWA, E

39

11

2819-2829