(Q46342369)

English

Critical Aspects of Heme-Peroxo-Cu Complex Structure and Nature of Proton Source Dictate Metal-O(peroxo) Breakage versus Reductive O-O Cleavage Chemistry.

scientific article published on 28 December 2016

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Europe PubMed Central

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4 April 2020

Critical Aspects of Heme-Peroxo-Cu Complex Structure and Nature of Proton Source Dictate Metal-O(peroxo) Breakage versus Reductive O-O Cleavage Chemistry (English)

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4 April 2020

Andrew W Schaefer

3

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4 April 2020

Kenneth D. Karlin

7

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4 April 2020

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Suzanne M Adam

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4 April 2020

Isaac Garcia-Bosch

2

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4 April 2020

Savita K Sharma

4

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4 April 2020

Maxime A Siegler

5

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4 April 2020

Edward I Solomon

6

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4 April 2020

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28 December 2016

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4 April 2020

Journal of the American Chemical Society

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4 April 2020

139

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4 April 2020

1

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4 April 2020

472-481

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4 April 2020

Using Biosynthetic Models of Heme-Copper Oxidase and Nitric Oxide Reductase in Myoglobin to Elucidate Structural Features Responsible for Enzymatic Activities

1 reference

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24 May 2018

Design and engineering of artificial oxygen-activating metalloenzymes

1 reference

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24 May 2018

Oxidation Reactions with Bioinspired Mononuclear Non-Heme Metal-Oxo Complexes

1 reference

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24 May 2018

A broken-symmetry density functional study of structures, energies, and protonation states along the catalytic O-O bond cleavage pathway in ba3 cytochrome c oxidase from Thermus thermophilus

1 reference

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24 May 2018

Spectroscopic and Crystallographic Evidence for the Role of a Water-Containing H-Bond Network in Oxidase Activity of an Engineered Myoglobin

1 reference

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24 May 2018

Electrocatalytic O2-Reduction by Synthetic Cytochrome c Oxidase Mimics: Identification of a "Bridging Peroxo" Intermediate Involved in Facile 4e(-)/4H(+) O2-Reduction

1 reference

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24 May 2018

Synthetic heme/copper assemblies: toward an understanding of cytochrome c oxidase interactions with dioxygen and nitrogen oxides.

1 reference

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24 May 2018

Moving protons and electrons in biomimetic systems

1 reference

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24 May 2018

Defining the role of tyrosine and rational tuning of oxidase activity by genetic incorporation of unnatural tyrosine analogs

1 reference

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24 May 2018

Reaction mechanism of cytochrome c oxidase

1 reference

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24 May 2018

A "naked" Fe(III)-(O₂²⁻)-Cu(II) species allows for structural and spectroscopic tuning of low-spin heme-peroxo-Cu complexes

1 reference

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24 May 2018

Status of reactive non-heme metal-oxygen intermediates in chemical and enzymatic reactions.

1 reference

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24 May 2018

Copper active sites in biology

1 reference

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24 May 2018

Density functional study for the bridged dinuclear center based on a high-resolution X-ray crystal structure of ba3 cytochrome c oxidase from Thermus thermophilus

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=5274545

24 May 2018

Stepwise protonation and electron-transfer reduction of a primary copper-dioxygen adduct

1 reference

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24 May 2018

A selective stepwise heme oxygenase model system: an iron(IV)-oxo porphyrin π-cation radical leads to a verdoheme-type compound via an isoporphyrin intermediate

1 reference

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24 May 2018

Differential hydrogen bonding in human CYP17 dictates hydroxylation versus lyase chemistry

1 reference

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24 May 2018

Enhanced catalytic four-electron dioxygen (O2) and two-electron hydrogen peroxide (H2O2) reduction with a copper(II) complex possessing a pendant ligand pivalamido group

1 reference

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24 May 2018

CO, NO and O2 as Vibrational Probes of Heme Protein Interactions

1 reference

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24 May 2018

Significant increase of oxidase activity through the genetic incorporation of a tyrosine-histidine cross-link in a myoglobin model of heme-copper oxidase

1 reference

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24 May 2018

Structural studies on bovine heart cytochrome c oxidase

1 reference

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24 May 2018

Electronic structure of a low-spin heme/Cu peroxide complex: spin-state and spin-topology contributions to reactivity

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=5274545

24 May 2018

Cytochrome c oxidase: Intermediates of the catalytic cycle and their energy-coupled interconversion

1 reference

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24 May 2018

Homogeneous catalytic O2 reduction to water by a cytochrome c oxidase model with trapping of intermediates and mechanistic insights

1 reference

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24 May 2018

The O(2) reduction and proton pumping gate mechanism of bovine heart cytochrome c oxidase

1 reference

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24 May 2018

Proton coupled electron transfer and redox active tyrosines in Photosystem II

1 reference

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24 May 2018

Dioxygen activation in soluble methane monooxygenase

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24 May 2018

Investigation of the mechanism of formation of a thiolate-ligated Fe(III)-OOH

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24 May 2018

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24 May 2018

Proton-coupled electron transfer in cytochrome oxidase.

1 reference

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24 May 2018

Functional Models for the Oxygen-Evolving Complex of Photosystem II.

1 reference

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24 May 2018

Thermochemistry of proton-coupled electron transfer reagents and its implications

1 reference

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24 May 2018

Quantum Chemical Studies of Proton-Coupled Electron Transfer in Metalloenzymes

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=5274545

24 May 2018

Bovine cytochrome c oxidase structures enable O 2 reduction with minimization of reactive oxygens and provide a proton-pumping gate

1 reference

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24 May 2018

Role of the secondary coordination sphere in metal-mediated dioxygen activation

1 reference

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24 May 2018

Thermodynamic equilibrium between blue and green copper sites and the role of the protein in controlling function

1 reference

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24 May 2018

Functional biomimetic models for the active site in the respiratory enzyme cytochrome c oxidase

1 reference

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24 May 2018

Prediction of acidity in acetonitrile solution with COSMO-RS

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24 May 2018

The proton donor for O-O bond scission by cytochrome c oxidase

1 reference

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24 May 2018

Resonance Raman characterization of the peroxo and hydroperoxo intermediates in cytochrome P450.

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24 May 2018

Enzymes as working or inspirational electrocatalysts for fuel cells and electrolysis

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24 May 2018

Spectroscopic and kinetic studies of perturbed trinuclear copper clusters: the role of protons in reductive cleavage of the O-O bond in the multicopper oxidase Fet3p

1 reference

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24 May 2018

Reactivity studies on Fe(III)-(O2(2-))-Cu(II) compounds: influence of the ligand architecture and copper ligand denticity.

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24 May 2018

Heme-copper/dioxygen adduct formation, properties, and reactivity

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24 May 2018

Mononuclear Cu-O2 complexes: geometries, spectroscopic properties, electronic structures, and reactivity

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24 May 2018

A cytochrome C oxidase model catalyzes oxygen to water reduction under rate-limiting electron flux

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24 May 2018

Structure and chemistry of cytochrome P450.

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24 May 2018

Dioxygen reactivity of copper and heme-copper complexes possessing an imidazole-phenol cross-link.

1 reference

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24 May 2018

Oxidant types in copper-dioxygen chemistry: the ligand coordination defines the Cu(n)-O2 structure and subsequent reactivity

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24 May 2018

Synthetic models for heme-copper oxidases

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24 May 2018

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24 May 2018

From water to oxygen and back again: mechanistic similarities in the enzymatic redox conversions between water and dioxygen

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24 May 2018

Mechanism of Oxygen Reduction in Cytochrome c Oxidase and the Role of the Active Site Tyrosine.

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15 August 2018

Saturation kinetics in phenolic O-H bond oxidation by a mononuclear Mn(III)-OH complex derived from dioxygen.

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15 August 2018

Very strong organosuperbases formed by combining imidazole and guanidine bases: synthesis, structure, and basicity

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15 August 2018

Editorial for the virtual issue on models of metalloenzymes.

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15 August 2018

Interaction between substrate and oxygen ligand responsible for effective O-O bond cleavage in bovine cytochrome P450 steroid 21-hydroxylase proved by Raman spectroscopy

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15 August 2018

Life with oxygen

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15 August 2018

Proton-directed redox control of O-O bond activation by heme hydroperoxidase models.

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15 August 2018

Application of Badger's rule to heme and non-heme iron-oxygen bonds: an examination of ferryl protonation states.

1 reference

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15 August 2018

Oxidation mechanism of phenols by dicopper-dioxygen (Cu(2)/O(2)) complexes

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15 August 2018

Metal-bridging mechanism for O-O bond cleavage in cytochrome C oxidase

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15 August 2018

Spectroscopic evidence for a heme-superoxide/Cu(I) intermediate in a functional model of cytochrome c oxidase

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15 August 2018

A bis-acetonitrile two-coordinate copper(I) complex: synthesis and characterization of highly soluble B(C(6)F(5))(4)(-) salts of [Cu(MeCN)(2)](+) and [Cu(MeCN)(4)](+).

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15 August 2018

Structure-spectroscopy correlation in distorted five-coordinate Cu(II) complexes: a case study with a set of closely related copper complexes of pyridine-2,6-dicarboxamide ligands

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15 August 2018

(F(8)TPP)Fe(II)/O(2) reactivity studies [F(8)TPP = tetrakis(2,6-difluorophenyl)porphyrinate(2-)]: spectroscopic (UV-Visible and NMR) and kinetic study of solvent-dependent (Fe/O(2) = 1:1 or 2:1) reversible O(2)-reduction and ferryl formation

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15 August 2018

Effect of Protonation on Peroxo-Copper Bonding: Spectroscopic and Electronic Structure Study of [Cu(2)((UN-O-)(OOH)](2+).

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15 August 2018

Copper Hydroperoxo Species Activated by Hydrogen-Bonding Interaction with Its Distal Oxygen

1 reference

https://pubmed.ncbi.nlm.nih.gov/28029788

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Solar energy supply and storage for the legacy and nonlegacy worlds

1 reference

https://pubmed.ncbi.nlm.nih.gov/28029788

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Stabilization of the peroxy intermediate in the oxygen splitting reaction of cytochrome cbb(3)

1 reference

https://pubmed.ncbi.nlm.nih.gov/28029788

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Standard Reduction Potentials for Oxygen and Carbon Dioxide Couples in Acetonitrile and N,N-Dimethylformamide

1 reference

https://pubmed.ncbi.nlm.nih.gov/28029788

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Preface: biomimetic inorganic chemistry

1 reference

https://pubmed.ncbi.nlm.nih.gov/28029788

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Electrocatalytic oxygen reduction by iron tetra-arylporphyrins bearing pendant proton relays

1 reference

https://pubmed.ncbi.nlm.nih.gov/28029788

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Oxygen activation and reduction in respiration: involvement of redox-active tyrosine 244

1 reference

https://pubmed.ncbi.nlm.nih.gov/28029788

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Ferryl and hydroxy intermediates in the reaction of oxygen with reduced cytochrome c oxidase.

1 reference

https://pubmed.ncbi.nlm.nih.gov/28029788

12 December 2020

based on heuristic

inferred from PubMed ID database lookup

Identifiers

10.1021/JACS.6B11322

1 reference

Europe PubMed Central

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https://www.ebi.ac.uk/europepmc/webservices/rest/search?query=EXT_ID:28029788%20AND%20SRC:MED&resulttype=core&format=json

4 April 2020

PMC publication ID

1 reference

Europe PubMed Central

PMC publication ID

https://www.ebi.ac.uk/europepmc/webservices/rest/search?query=EXT_ID:28029788%20AND%20SRC:MED&resulttype=core&format=json

4 April 2020

PubMed publication ID

1 reference

Europe PubMed Central

PMC publication ID

https://www.ebi.ac.uk/europepmc/webservices/rest/search?query=EXT_ID:28029788%20AND%20SRC:MED&resulttype=core&format=json

4 April 2020

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