(Q58056627)

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Catalytic functionalization of unactivated primary C–H bonds directed by an alcohol

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Catalytic functionalization of unactivated primary C–H bonds directed by an alcohol (English)

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John F. Hartwig

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John F. Hartwig

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Eric M. Simmons

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publication date

March 2012

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483

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7387

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70-73

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C-H bond functionalization in complex organic synthesis

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C-H functionalization logic in total synthesis

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If C-H bonds could talk: selective C-H bond oxidation

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Total synthesis of eudesmane terpenes by site-selective C-H oxidations.

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Evaluation of the donor ability of phenanthrolines in iridium complexes by means of synchrotron radiation photoemission spectroscopy and DFT calculations

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Iridium-catalyzed arene ortho-silylation by formal hydroxyl-directed C-H activation

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C-H hydroxylation using a heterocyclic catalyst and aqueous H2O2.

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1,3-Diol synthesis via controlled, radical-mediated C-H functionalization

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Saponin and sapogenol. XLVIII. On the constituents of the roots of Glycyrrhiza uralensis Fischer from northeastern China. (2). Licorice-saponins D3, E2, F3, G2, H2, J2, and K2

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Synthesis of cyclopamine using a biomimetic and diastereoselective approach.

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Remote hydroxylation of methyl groups by regioselective cyclopalladation. Partial synthesis of hyptatic acid-A

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C−H Activation for the Construction of C−B Bonds

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Direct construction of 1,3-diaxial diol derivatives by C-H hydroxylation

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A predictably selective aliphatic C-H oxidation reaction for complex molecule synthesis

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Recent developments in natural product synthesis using metal-catalysed C-H bond functionalisation

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Pd-catalyzed stereoselective oxidation of methyl groups by inexpensive oxidants under mild conditions: a dual role for carboxylic anhydrides in catalytic C--H bond oxidation

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Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions

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Palladium-catalyzed oxygenation of unactivated sp3 C-H bonds

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Total synthesis of celogentin C by stereoselective C-H activation.

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Metal-catalyzed oxidations of C-H to C-N bonds

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Statistical Investigation into the Structural Complementarity of Natural Products and Synthetic Compounds

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Synthesis ofα-Hederin,δ-Hederin, and Related Triterpenoid Saponins

1 reference

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10.1038/NATURE10785

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