(Q46917677)

26 December 2017

title

Unexpected oxidation of a depsipeptide substrate analogue in crystalline isopenicillin N synthase (English)

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26 December 2017

5

Peter J Rutledge

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author name string

Adam Daruzzaman

1

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26 December 2017

Ian J Clifton

2

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26 December 2017

Robert M Adlington

3

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26 December 2017

Jack E Baldwin

4

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26 December 2017

Peter J Rutledge

5

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26 December 2017

publication date

1 February 2006

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26 December 2017

published in

ChemBioChem

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26 December 2017

volume

7

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26 December 2017

issue

2

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26 December 2017

page(s)

351-358

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26 December 2017

The biosynthesis of penicillins and cephalosporins

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Thiolate ligation of the active site Fe2+ of isopenicillin N synthase derives from substrate rather than endogenous cysteine: spectroscopic studies of site-specific Cys----Ser mutated enzymes

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Crystal structure of isopenicillin N synthase is the first from a new structural family of enzymes

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Structure of isopenicillin N synthase complexed with substrate and the mechanism of penicillin formation

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The reaction cycle of isopenicillin N synthase observed by X-ray diffraction

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Alternative oxidation by isopenicillin N synthase observed by X-ray diffraction

21 January 2018

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Crystallographic studies on the reaction of isopenicillin N synthase with an unsaturated substrate analogue

21 January 2018

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Structural studies on the reaction of isopenicillin N synthase with the substrate analogue delta-(l-alpha-aminoadipoyl)-l-cysteinyl-d-alpha-aminobutyrate

21 January 2018

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Structural studies on the reaction of isopenicillin N synthase with the truncated substrate analogues delta-(L-alpha-aminoadipoyl)-L-cysteinyl-glycine and delta-(L-alpha-aminoadipoyl)-L-cysteinyl-D-alanine

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21 January 2018

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Active-site-mediated elimination of hydrogen fluoride from a fluorinated substrate analogue by isopenicillin N synthase

21 January 2018

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X-ray absorption studies of the ferrous active site of isopenicillin N synthase and related model complexes

21 January 2018

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Glutamine-330 is not essential for activity in isopenicillin N synthase from Aspergillus nidulans

21 January 2018

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Anaerobic Crystallisation of an Isopenicillin N Synthase . Fe(II) . Substrate Complex Demonstrated by X-Ray Studies

21 January 2018

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A device for the high-pressure oxygenation of protein crystals

21 January 2018

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21 January 2018

Identifiers

DOI

10.1002/CBIC.200500282

1 reference

26 December 2017

1 reference

26 December 2017